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Effect of hydrogen bonding on a value of an open circuit potential of poly-(3,4-ethylenedioxythiophene) as a beneficial mode for energy storage devices

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F21%3A00543673" target="_blank" >RIV/61389013:_____/21:00543673 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216208:11310/21:10430927

  • Result on the web

    <a href="https://onlinelibrary.wiley.com/doi/10.1002/adfm.202103001" target="_blank" >https://onlinelibrary.wiley.com/doi/10.1002/adfm.202103001</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/adfm.202103001" target="_blank" >10.1002/adfm.202103001</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Effect of hydrogen bonding on a value of an open circuit potential of poly-(3,4-ethylenedioxythiophene) as a beneficial mode for energy storage devices

  • Original language description

    Poly(3,4-ethylenedioxythiophene) is one of the semiconducting polymers that has attracted attention as electroactive materials for many different applications such as electrochromic devices, light-emitting diodes, biosensors, and supercapacitors. The fundamental understanding of the origin of its energy storage ability will lead to the proper design of such devices. Generally, the charge storage in supercapacitors is due to the formation of an electrical double layer and/or redox reactions. Recently, it is shown that the formation of cation radicals in PEDOT is induced by the hydrogen-bond formation between formic acid and polymer during electrochemical polymerization. The induced cation radicals play a major role in the charge storage ability of PEDOT, as studied in the current work. Furthermore, the presence of hydrogen bonds in PEDOT leads to the stable in time open circuit potential of 900 mV. This new knowledge leads to the designing of a symmetrical supercapacitor based on PEDOT as active material where hydrogen-bonds play a crucial role in the improved performance of the device.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10404 - Polymer science

Result continuities

  • Project

    <a href="/en/project/GA19-04859S" target="_blank" >GA19-04859S: Interaction of conducting polymers with organic dyes: Principles and consequences</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2021

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Advanced Functional Materials

  • ISSN

    1616-301X

  • e-ISSN

    1616-3028

  • Volume of the periodical

    31

  • Issue of the periodical within the volume

    28

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    7

  • Pages from-to

    2103001

  • UT code for WoS article

    000643430300001

  • EID of the result in the Scopus database

    2-s2.0-85104822774