Compositional distribution of binary living copolymers and their end sequences
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F21%3A00544171" target="_blank" >RIV/61389013:_____/21:00544171 - isvavai.cz</a>
Result on the web
<a href="https://onlinelibrary.wiley.com/doi/10.1002/mats.202100002" target="_blank" >https://onlinelibrary.wiley.com/doi/10.1002/mats.202100002</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/mats.202100002" target="_blank" >10.1002/mats.202100002</a>
Alternative languages
Result language
angličtina
Original language name
Compositional distribution of binary living copolymers and their end sequences
Original language description
Statistical analysis is carried out for the compositional distribution (CD) of binary copolymers prepared by living copolymerization. The CDs of both block and random (Bernoullian) binary copolymers are found to be the product of two Poisson distributions. The analysis is further developed for instantaneous first-order Markovian copolymers (the terminal model). The relations are derived for the CD of i) copolymers with fixed polymerization degree and ii) of copolymers with variable polymerization degree. The relations ad (i) describe also CD of copolymer end sequences. However, they cannot be used for interpretation of tandem mass spectrometry where end-sequence CD for isobaric copolymers is required. Such relations are also derived. Stepwise application of the equations affords approximation of high-conversion living copolymerization. Fair agreement of the derived relations with kinetic Monte–Carlo simulation and qualitative agreement with the experimental data on n-butyl acrylate/methyl methacrylate copolymers prepared by quasi-living radical polymerization is found.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10404 - Polymer science
Result continuities
Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Macromolecular Theory and Simulations
ISSN
1022-1344
e-ISSN
1521-3919
Volume of the periodical
30
Issue of the periodical within the volume
4
Country of publishing house
DE - GERMANY
Number of pages
12
Pages from-to
2100002
UT code for WoS article
000643423500001
EID of the result in the Scopus database
2-s2.0-85104869988