Polymerization of renewable itaconic acid in deep eutectic monomers: effect of the quaternary ammonium cation structure
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F24%3A00580221" target="_blank" >RIV/61389013:_____/24:00580221 - isvavai.cz</a>
Result on the web
<a href="https://www.sciencedirect.com/science/article/pii/S0014305723008601?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0014305723008601?via%3Dihub</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.eurpolymj.2023.112677" target="_blank" >10.1016/j.eurpolymj.2023.112677</a>
Alternative languages
Result language
angličtina
Original language name
Polymerization of renewable itaconic acid in deep eutectic monomers: effect of the quaternary ammonium cation structure
Original language description
A systematic investigation has been carried out on the synthesis of poly(itaconic acid) (PIA) in Deep Eutectic Monomer (DEM) systems, composed of bio-derived itaconic acid (IA) and quaternary ammonium chlorides (QCl) varying in their cation structure. The physicochemical properties including density, viscosity, Kamlet-Taft parameters and polarity as Nile Red transition energy of DEMs supported with spectroscopic studies (FT-IR, 1H and 13C NMR) are reported. It was observed that cation structure of the ammonium chloride impacts on the physicochemical properties and radical polymerization of DEMs. More notably, the correlations between the Kamlet-Taft hydrogen bonding accepting ability (β) of the DEMs and both IA polymerization rate and the molecular weight of the synthesized PIA were found. These findings provided theoretical guidance on designing DEMs tailored to specific polymerization process.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10404 - Polymer science
Result continuities
Project
<a href="/en/project/GF21-07004K" target="_blank" >GF21-07004K: Biomass-derived itaconic acid-based polyelectrolytes for synthesis of self-assembled nanocomposite hydrogels</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
European Polymer Journal
ISSN
0014-3057
e-ISSN
1873-1945
Volume of the periodical
203
Issue of the periodical within the volume
19 January
Country of publishing house
GB - UNITED KINGDOM
Number of pages
10
Pages from-to
112677
UT code for WoS article
001145707000001
EID of the result in the Scopus database
2-s2.0-85180754100