Gold(I)-thiolate coordination polymers as multifunctional materials: the case of Au(I)-p-fluorothiophenolate
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F24%3A00585871" target="_blank" >RIV/61389013:_____/24:00585871 - isvavai.cz</a>
Alternative codes found
RIV/68407700:21670/24:00376031
Result on the web
<a href="https://pubs.acs.org/doi/10.1021/acsami.4c01958" target="_blank" >https://pubs.acs.org/doi/10.1021/acsami.4c01958</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acsami.4c01958" target="_blank" >10.1021/acsami.4c01958</a>
Alternative languages
Result language
angličtina
Original language name
Gold(I)-thiolate coordination polymers as multifunctional materials: the case of Au(I)-p-fluorothiophenolate
Original language description
Gold–sulfur interaction has vital importance in nanotechnologies and material chemistry to design functional nanoparticles, self-assembled monolayers, or molecular complexes. In this paper, a mixture of only two basic precursors, such as the chloroauric acid (HAu(III)Cl4) and a thiol molecule (p-fluorothiophenol (p-HSPhF)), are used for the synthesis of gold(I)–thiolate coordination polymers. Under different conditions of synthesis and external stimuli, five different functional materials with different states of [Au(I)(p-SPhF)]n can be afforded. These gold–thiolate compounds are (i) red emissive, flexible, and crystalline fibers, (ii) composite materials made of these red emissive fibers and gold nanoparticles, (iii) amorphous phase, (iv) transparent glass, and (v) amorphous-to-crystalline phase-change material associated with an ON/OFF switch of luminescence. The different functionalities of these materials highlight the great versatility of the gold(I) thiolate coordination polymers with easy synthesis and diverse shaping that may have great potential as sustainable phosphors, smart textiles, sensors, and phase change memories.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
20501 - Materials engineering
Result continuities
Project
<a href="/en/project/GA22-02005S" target="_blank" >GA22-02005S: Exciton transformation in supramolecular polymers for energy conversion</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ACS Applied Materials and Interfaces
ISSN
1944-8244
e-ISSN
1944-8252
Volume of the periodical
16
Issue of the periodical within the volume
17
Country of publishing house
US - UNITED STATES
Number of pages
10
Pages from-to
22512-22521
UT code for WoS article
001242239400001
EID of the result in the Scopus database
2-s2.0-85192009322