Dielectric Spectroscopy of Calcium Titanate Processed by Spark Plasma Sintering

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389021%3A_____%2F23%3A00583097" target="_blank" >RIV/61389021:_____/23:00583097 - isvavai.cz</a>

Alternative codes found

RIV/68407700:21230/23:00369242

Result on the web

<a href="https://www.mdpi.com/1996-1944/16/3/975" target="_blank" >https://www.mdpi.com/1996-1944/16/3/975</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/ma16030975" target="_blank" >10.3390/ma16030975</a>

Result language

angličtina

Original language name

Dielectric Spectroscopy of Calcium Titanate Processed by Spark Plasma Sintering

Original language description

Calcium titanate (CaTiO3) powder was compacted by spark plasma sintering (SPS). The resulting products were subjected to the phase stability study and dielectric characterization. The change in temperature of SPS between 1100 °C and 1250 °C had a clear and straightforward effect on density, porosity, relative permittivity, loss tangent, and DC resistivity. Since the SPS itself introduces certain oxygen deficiency into Ti-perovskites, all samples were annealed after SPS. However, this post-processing did not mask the effects of the SPS regime. Optical reflectance measurements were completed to compare and quantify the sample coloration and support the dielectric results with corresponding optical band gap estimations. Subtle changes in the CaTiO3 crystal lattice arrangement, completed between 1150 °C and 1250 °C and documented in the literature for conventionally sintered samples, could not be confirmed for SPS-prepared calcium titanate. The novelty of this research work is in producing very stable dielectric ceramics and an indication of the SPS processing parameters suitable for this. The best sample showed at 1 MHz frequency the combination of relative permittivity 370, loss tangent 0.008, and DC resistivity 3 × 1012 Ωm.

Czech name

—

Czech description

—

Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

—

OECD FORD branch

20501 - Materials engineering

Project

—

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2023

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Materials

ISSN

1996-1944

e-ISSN

1996-1944

Volume of the periodical

16

Issue of the periodical within the volume

3

Country of publishing house

CH - SWITZERLAND

Number of pages

14

Pages from-to

975

UT code for WoS article

000929699100001

EID of the result in the Scopus database

2-s2.0-85147795981