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Dielectric Response and Low Dielectric Loss of Gadolinium-Doped CaCu3Ti4O12Ceramics Processed Through Conventional and Microwave Sintering

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389021%3A_____%2F23%3A00583134" target="_blank" >RIV/61389021:_____/23:00583134 - isvavai.cz</a>

  • Result on the web

    <a href="https://link.springer.com/article/10.1007/s11664-023-10341-w" target="_blank" >https://link.springer.com/article/10.1007/s11664-023-10341-w</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1007/s11664-023-10341-w" target="_blank" >10.1007/s11664-023-10341-w</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Dielectric Response and Low Dielectric Loss of Gadolinium-Doped CaCu3Ti4O12Ceramics Processed Through Conventional and Microwave Sintering

  • Original language description

    Gadolinium-doped (CaCu3Ti4O12/CCTO)x ceramics were fabricated using conventional (CS) and microwave sintering (MWS) at x = 0.1, 0.2 and 0.3. The green compacts were sintered at 1100°C via muffle and microwave furnace at 5°C min−1/12 h and 50°C min−1/30 min, respectively. A single pure cubic phase of CCTO for MWS and minor secondary phases for CS were revealed by x-ray diffraction (XRD) patterns. Scanning electron microscope (SEM) images showed a reduction in grain size from ~ 20.04 ± 8.43 µm to ~ 17.52 ± 7.77 µm and ~ 1.99 ± 0.44 µm to ~ 1.32 ± 0.27 µm for both CS and MWS. The charge carrier hopping between Cu+ and Ti3+ was probed using x-ray photoelectron spectroscopy (XPS), which confirmed the conductivity of grains and internal barrier layer capacitance (IBLC) effect. Broadband dielectric spectrometer findings revealed a dielectric constant of ɛ > 104 at 10 Hz and ɛ > 103 at 100 kHz for CS at x = 0.2 and ɛ > 102 at 10 Hz (x ≤ 0.2) for MWS. A very minimal tanδ of 0.08 (x = 0.2) was recorded at 100 kHz.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20504 - Ceramics

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2023

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Electronic Materials

  • ISSN

    0361-5235

  • e-ISSN

    1543-186X

  • Volume of the periodical

    52

  • Issue of the periodical within the volume

    6

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    11

  • Pages from-to

    3848-3858

  • UT code for WoS article

    000961215400002

  • EID of the result in the Scopus database

    2-s2.0-85151360341