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Streamer-induced kinetics of excited states in pure N2: II. Formation of N2(B3Πg,v=0-21) through analysis of emission produced by the first positive system

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389021%3A_____%2F24%3A00585669" target="_blank" >RIV/61389021:_____/24:00585669 - isvavai.cz</a>

  • Result on the web

    <a href="https://iopscience.iop.org/article/10.1088/1361-6595/ad1c09" target="_blank" >https://iopscience.iop.org/article/10.1088/1361-6595/ad1c09</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1088/1361-6595/ad1c09" target="_blank" >10.1088/1361-6595/ad1c09</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Streamer-induced kinetics of excited states in pure N2: II. Formation of N2(B3Πg,v=0-21) through analysis of emission produced by the first positive system

  • Original language description

    Vibrational distributions of electronically excited states of N2 obtained through dipole-allowed radiative transitions provide an important tool to study the kinetics of non-equilibrium plasmas under various discharge conditions. In this work, we report, for the first time, streamer-induced visible/near-infra-red emission spectra developing during the first hundred nanoseconds after the initiation of the discharge. Emission through the first positive system of N-2 was acquired in 500-1100 nm range, which allows a complete analysis of the N-2(B-3 pi(g),v = 0-21) vibrational manifold. The investigated evolution of the vibrational distribution of the N-2(B-3 pi g , v = 0-21) state at the centre of the gap corresponds to the transition of the streamer head and the subsequent decay of the streamer channel. We show that the vibrational distribution characterising streamer head is determined by Franck-Condon factors, while during streamer relaxation, it is influenced by the complex interaction between triplet excited states of N-2. Additionally, the observed N-2(B-3 pi(g) , v = 13-21) vibrational levels are likely produced by the interaction of high vibrational levels of N-2(W-3 Delta u , B' 3 Sigma(-)(u) , B (3)pi(g)) with N-2(C-3 pi(u)) state. We also provide a detailed kinetic scheme for modelling vibrationally-resolved N-2(B (3)pi(g) ) state and compare model results with experimental outcomes.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10305 - Fluids and plasma physics (including surface physics)

Result continuities

  • Project

    <a href="/en/project/GA15-04023S" target="_blank" >GA15-04023S: Advanced Research of Kinetic Processes in Streamer Discharges</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2024

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Plasma Sources Science & Technology

  • ISSN

    0963-0252

  • e-ISSN

    1361-6595

  • Volume of the periodical

    33

  • Issue of the periodical within the volume

    1

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    18

  • Pages from-to

    015011

  • UT code for WoS article

    001154750700001

  • EID of the result in the Scopus database

    2-s2.0-85184010258