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Photocatalytic nanostructured materials for heavy metal remediation: Mechanisms, challenges, and future prospects

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389021%3A_____%2F26%3A00648112" target="_blank" >RIV/61389021:_____/26:00648112 - isvavai.cz</a>

  • Result on the web

    <a href="https://www.sciencedirect.com/science/article/pii/S136980012501008X" target="_blank" >https://www.sciencedirect.com/science/article/pii/S136980012501008X</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.mssp.2025.110269" target="_blank" >10.1016/j.mssp.2025.110269</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Photocatalytic nanostructured materials for heavy metal remediation: Mechanisms, challenges, and future prospects

  • Original language description

    Heavy metal and metalloid contamination of aquatic environments poses significant ecological and health risks. Photocatalysis using nanostructured semiconductors offers a promising remediation approach by harnessing solar energy for simultaneous contaminant degradation and metal ion reduction. This review critically examines photocatalytic nanomaterials for heavy metal and metalloid remediation from wastewater, emphasizing mechanisms, performance metrics, and emerging challenges. Photocatalytic processes generate reactive species (center dot OH, center dot O-2(-) , photoelectrons) that reduce toxic metal ions (Cr(VI)-> Cr(III), Hg2+-> Hg-0) while degrading organic cocontaminants. Materials examined include metal oxide semiconductors (TiO2, ZnO, BiVO4), carbon nitride (gC(3)N(4)), and hybrid nanocomposites. This review provides: (1) comprehensive mechanistic analysis across material classes, (2) quantitative comparison of removal efficiencies and operational parameters, (3) critical evaluation of modification strategies (doping, heterojunction formation, plasmonic enhancement) for visible light activity, (4) assessment of nanomaterial integration with conventional treatment methods, (5) analysis of emerging materials (MXenes, MOF-derived carbons), and (6) discussion of scale-up challenges including photocatalyst stability, recovery, and environmental safety. While laboratory studies demonstrate high removal efficiencies (>90 % for many systems), challenges persist regarding cost-effectiveness, long-term stability, and real wastewater complexity. Future directions emphasize solar-driven systems, single-atom catalysts, and multifunctional photocatalysts for simultaneous multi-contaminant treatment. The adaptability and scalability of these nanomaterials enable integration into sustainable wastewater treatment systems and decentralized remediation units, with potential for resource recovery. Their solar-driven operation offers energy-efficient, ecofriendly solutions for industrial and municipal applications.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20704 - Energy and fuels

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2026

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Materials Science in Semiconductor Processing

  • ISSN

    1369-8001

  • e-ISSN

    1873-4081

  • Volume of the periodical

    204

  • Issue of the periodical within the volume

    March

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    33

  • Pages from-to

    110269

  • UT code for WoS article

    001628115300001

  • EID of the result in the Scopus database

    2-s2.0-105022437896