Ferromagnetic Properties of a Trinuclear Nickel(II) Complex with a Trithiocyanurate Bridge

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389030%3A_____%2F09%3A00337064" target="_blank" >RIV/61389030:_____/09:00337064 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Ferromagnetic Properties of a Trinuclear Nickel(II) Complex with a Trithiocyanurate Bridge

Original language description

A novel trinuclear nickel(II) komplex with N,N,N´,N´´,N´´-pentamethyldiethylenetriamine (pmdien) and a trithiocyanurate(3-) (ttc3-) bridge of composition [Ni3(pmdien) 3(?-ttc)](ClO4) 3 (1) was prepared. The X-ray crystal structure of 1 was determined, revealing the tris-N,S chelating mode of the trithiocyanurate bridge, forming a regular NiII3 core. A deformed trigonal bipyramidal arrangement of the central atoms was further achieved by coordination of tree pmdien N atoms. The complex show a ferromagnetic exchange interaction among the NiII magnetic center that is tuned by single-ion anisotropy and/or antisymetric exchange. The complex orders ferromagnetically at Tc=10K and exhibits spin-glass properties.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CE - Biochemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2009

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

European Journal of Inorganic Chemistry

ISSN

1434-1948

e-ISSN

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Volume of the periodical

2009

Issue of the periodical within the volume

36

Country of publishing house

DE - GERMANY

Number of pages

8

Pages from-to

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UT code for WoS article

000273378100002

EID of the result in the Scopus database

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