Symmetric Ni(II) dithiocarbamates with bidentate phosphines ligands

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61988987%3A17310%2F06%3AA0900GR1" target="_blank" >RIV/61988987:17310/06:A0900GR1 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Symmetric Ni(II) dithiocarbamates with bidentate phosphines ligands

Original language description

Ni(II) mononuclear dithiocarbamate complexes with bidentate P, P ligands of composition [Ni(R(2)dtc)(P, P)]X {R = pentyl (pe), benzyl (bz); dtc = S2CN-; P,P = 1,2-bis(diphenylphosphino) ethane (dppe), 1,4-bis(diphenylphosphino)butane (dppb), 1,1'-bis(diphenylphosphino) ferrocene (dppf); X = ClO4, Cl, Br, NCS} and binuclear complexes of composition [Ni-2(mu-dpph)(R(2)dtc)(2)]X-2 with a P,P-bridging ligand {P,P = 1,6-bis(diphenylphosphino) hexane (dpph); X = Cl, Br, NCS} have been synthesized. The complexes have been characterized by elemental and thermal analysis, IR, electronic and P-31{H-1}-NMR spectroscopy, magnetochemical and conductivity measurements. Single crystal X-ray analysis of [Ni(pe(2)dtc)( dppf)]ClO4 confirmed a distorted square planar coordination in the NiS2P2 chromophore. For selected samples, the catalysis of graphite oxidation was studied.

Czech name

Symmetric Ni(II) dithiocarbamates with bidentate phosphines ligands

Czech description

Ni(II) mononuclear dithiocarbamate complexes with bidentate P, P ligands of composition [Ni(R(2)dtc)(P, P)]X {R = pentyl (pe), benzyl (bz); dtc = S2CN-; P,P = 1,2-bis(diphenylphosphino) ethane (dppe), 1,4-bis(diphenylphosphino)butane (dppb), 1,1'-bis(diphenylphosphino) ferrocene (dppf); X = ClO4, Cl, Br, NCS} and binuclear complexes of composition [Ni-2(mu-dpph)(R(2)dtc)(2)]X-2 with a P,P-bridging ligand {P,P = 1,6-bis(diphenylphosphino) hexane (dpph); X = Cl, Br, NCS} have been synthesized. The complexes have been characterized by elemental and thermal analysis, IR, electronic and P-31{H-1}-NMR spectroscopy, magnetochemical and conductivity measurements. Single crystal X-ray analysis of [Ni(pe(2)dtc)( dppf)]ClO4 confirmed a distorted square planar coordination in the NiS2P2 chromophore. For selected samples, the catalysis of graphite oxidation was studied.

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

S - Specificky vyzkum na vysokych skolach

Publication year

2006

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

JOURNAL OF COORDINATION CHEMISTRY

ISSN

0095-8972

e-ISSN

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Volume of the periodical

5

Issue of the periodical within the volume

8

Country of publishing house

GB - UNITED KINGDOM

Number of pages

9

Pages from-to

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UT code for WoS article

000238247800009

EID of the result in the Scopus database

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