Porous carbon monoliths from ice-NaOH templated dissolved cellulose

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61988987%3A17310%2F22%3AA2302C75" target="_blank" >RIV/61988987:17310/22:A2302C75 - isvavai.cz</a>
Result on the web
<a href="https://www.sciencedirect.com/science/article/pii/S0926669022004447" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0926669022004447</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.indcrop.2022.114961" target="_blank" >10.1016/j.indcrop.2022.114961</a>

Result language
angličtina
Original language name
Porous carbon monoliths from ice-NaOH templated dissolved cellulose
Original language description
A simple and environmentally friendly route for the transformation of cellulose to porous carbon monoliths was developed. The procedure is based on freezing the cellulose solution in aqueous NaOH (-10 degrees C), followed by a direct regeneration of the frozen material in an ethanol bath and washing the alkaline with water. After atmospheric drying, the obtained cellulose monoliths composed mainly of cellulose II polymorph showed considerable macroporosity related to an ice-templating effect. During carbonization (500-900 degrees C, carbon yield > 20%) the macroporosity (approximate to 1-100 mu m) was preserved together with monolithic character. The resulting monolithic carbons also showed significant microporosity, with micropore volume up to 0.25 cm(3)/g, depending on carbonization temperature.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10406 - Analytical chemistry

Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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