Thickness-controlled porous hexagonal NiO nanodiscs electrodes for use in supercapacitors: How nanodiscs thickness influences electrochemical performance

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61988987%3A17310%2F22%3AA2302F6T" target="_blank" >RIV/61988987:17310/22:A2302F6T - isvavai.cz</a>

Result on the web

<a href="https://www.sciencedirect.com/science/article/pii/S2352152X2200353X?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S2352152X2200353X?via%3Dihub</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.est.2022.104329" target="_blank" >10.1016/j.est.2022.104329</a>

Result language

angličtina

Original language name

Thickness-controlled porous hexagonal NiO nanodiscs electrodes for use in supercapacitors: How nanodiscs thickness influences electrochemical performance

Original language description

Two-dimensional (2D) nickel oxide (NiO) hexagonal nanodiscs were synthesized via a hydrothermal route, followed by successive calcination. The decisive roles of the [OH-]/[Ni2+] molar ratios, as well as the calcination temperatures, were found in controlling the nanodiscs morphology of the NiO nanostructures. The increase in the concentration of OH- ions in the precursor solution influenced the crystal growth that directed to the formation of the hexagonal nanodisc morphology with increased edge thickness and beyond certain limits transformation from the nanodiscs to complete 3D morphology. The nanodiscs grew with increasing exposed surface size with a high BET area and varied thicknesses from 4 to 20 nm. The increase in calcination temperature improved crystallinity by eliminating crystal defects and voids, while crystals grew along the (200) plane. However, a reduction in the BET area and pore volume occurred at higher calcination temperature because of the collapse in micro-mesopores. The electrochemical performances of NiO electrodes show dependence on the thickness of the nanodiscs, the calcination temperature, and the type of current collector used. A distinct electrochemical feature was observed for NiO nanodiscs over planar conductive carbon fiber paper and 3D porous Ni foam substrates. The hydrothermal approach reported here to produce thickness-controlled NiO nanodiscs with high intrinsic surface area has great potential for developing next-generation battery-type faradic electrodes in conjunction with carbon allotropes and other metal oxide materials for high power and energy density throughput.

Czech name

—

Czech description

—

Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

—

OECD FORD branch

10400 - Chemical sciences

Project

<a href="/en/project/EF18_053%2F0017856" target="_blank" >EF18_053/0017856: Strengthening the university's scientific capacities II</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2022

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

JOURNAL OF ENERGY STORAGE

ISSN

2352-152X

e-ISSN

2352-152X

Volume of the periodical

—

Issue of the periodical within the volume

JUN 2022

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

13

Pages from-to

1-13

UT code for WoS article

000780268500003

EID of the result in the Scopus database

—