A New Member of the Metal-Porphyrin Frameworks Family: Structure, Physicochemical Properties, Hydrogen and Carbon Dioxide Adsorption
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61988987%3A17310%2F23%3AA2402MG8" target="_blank" >RIV/61988987:17310/23:A2402MG8 - isvavai.cz</a>
Result on the web
<a href="https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/open.202300100" target="_blank" >https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/open.202300100</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/open.202300100" target="_blank" >10.1002/open.202300100</a>
Alternative languages
Result language
angličtina
Original language name
A New Member of the Metal-Porphyrin Frameworks Family: Structure, Physicochemical Properties, Hydrogen and Carbon Dioxide Adsorption
Original language description
A novel holmium-based porous metal-porphyrin framework, {(H3O+)[Ho(H2TPPS)]− ⋅ 4H2O}n (denoted as UPJS-17), was synthesised by hydrothermal reaction. Structural analysis reveals, that UPJS-17 has a three-dimensional open framework. The framework is negatively charged and the negative charge is compensated by hydronium cation. The compound showed no N2 adsorption but the Ar, CO2 and H2. From the argon adsorption, the surface area of ~150 m2 g−1 was determined. Carbon dioxide adsorption was measured at various temperatures (0, 10, 20, 30 and 40 °C) and the compound showed the highest adsorption capacity (at 0 °C) of 7.0 wt % of CO2. From the carbon dioxide adsorption isotherms the isosteric heat of 56,5 kJ mol−1 was determined. Hydrogen adsorption was studied at −196 °C with hydrogen uptake of 2.1 wt % at 1 bar.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10400 - Chemical sciences
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2023
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemistryopen
ISSN
2191-1363
e-ISSN
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Volume of the periodical
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Issue of the periodical within the volume
2023-11-28
Country of publishing house
DE - GERMANY
Number of pages
7
Pages from-to
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UT code for WoS article
001102633900001
EID of the result in the Scopus database
2-s2.0-85176117598