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Phase transitions in free water nanoparticles. Theoretical modeling of [H2O](48) and [H2O](118)

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27240%2F15%3A86094706" target="_blank" >RIV/61989100:27240/15:86094706 - isvavai.cz</a>

  • Alternative codes found

    RIV/61989100:27740/15:86094706

  • Result on the web

    <a href="http://pubs.rsc.org/en/Content/ArticleLanding/2015/CP/C4CP04909H#!divAbstract" target="_blank" >http://pubs.rsc.org/en/Content/ArticleLanding/2015/CP/C4CP04909H#!divAbstract</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1039/c4cp04909h" target="_blank" >10.1039/c4cp04909h</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Phase transitions in free water nanoparticles. Theoretical modeling of [H2O](48) and [H2O](118)

  • Original language description

    Classical parallel-tempering Monte Carlo simulations of [H2O](48) and [H2O](118) have been performed in the isothermal-isobaric ensemble and a two-dimensional multiple-histogram method has been used to calculate the heat capacity of the two clusters. A semiempirical procedure is proposed for the inclusion of quantum effects and transformed heat capacity profiles are compared with state-of-the-art experimental data [C. Hock et al., Phys. Rev. Lett., 2009, 103, 073401]. A very good agreement is achieved.A detailed analysis of the simulation data is provided to gain an insight into the nature of the phase change which takes place in the two clusters at T approximate to 100 K.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/ED1.1.00%2F02.0070" target="_blank" >ED1.1.00/02.0070: IT4Innovations Centre of Excellence</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2015

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Physical Chemistry Chemical Physics

  • ISSN

    1463-9076

  • e-ISSN

  • Volume of the periodical

    17

  • Issue of the periodical within the volume

    16

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    6

  • Pages from-to

    10532-10537

  • UT code for WoS article

    000352707200025

  • EID of the result in the Scopus database

    2-s2.0-84927925614