Flashpoint prediction for binary mixtures of alcohols with water in order to improve their safety
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27350%2F15%3A86090524" target="_blank" >RIV/61989100:27350/15:86090524 - isvavai.cz</a>
Alternative codes found
RIV/61989100:27650/15:86090524 RIV/61989100:27200/15:86090524
Result on the web
<a href="http://dx.doi.org/10.1002/ceat.201400663" target="_blank" >http://dx.doi.org/10.1002/ceat.201400663</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/ceat.201400663" target="_blank" >10.1002/ceat.201400663</a>
Alternative languages
Result language
angličtina
Original language name
Flashpoint prediction for binary mixtures of alcohols with water in order to improve their safety
Original language description
Aqueous solutions of alcohols have for many years, and still today, been of considerable interest to a wide range of scientists and technologists. This paper presents the simple dimensionless experimental formulae based on rational reciprocal and polynomial functions for correlation of the flashpoint data of binary mixtures of two components. The formulae are based on data obtained from flashpoint experiments and predictions. The liquid-phase activity coefficients for CnH2n+1OH (n=1-5) binary aqueous-organic mixtures were estimated using the Wilson, NTRL and UNIQUAC equations. To confirm the predictive efficiency of the derived flashpoint approximated values, the model was verified by comparing the predicted values with the experimental data for the studied mixtures. Potential application for the model concerns the assessment of fire and explosion hazards, and the development of inherently safer designs for chemical processes containing binary partially miscible mixtures of an aqueous-
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CI - Industrial chemistry and chemical engineering
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemical Engineering and Technology
ISSN
0930-7516
e-ISSN
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Volume of the periodical
38
Issue of the periodical within the volume
4
Country of publishing house
DE - GERMANY
Number of pages
7
Pages from-to
727-733
UT code for WoS article
000352111200021
EID of the result in the Scopus database
2-s2.0-84925369322