Development of Porous Coatings Enriched with Magnesium and Zinc Obtained by DC Plasma Electrolytic Oxidation

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27350%2F18%3A10239156" target="_blank" >RIV/61989100:27350/18:10239156 - isvavai.cz</a>

Result on the web

<a href="https://www.mdpi.com/2072-666X/9/7/332" target="_blank" >https://www.mdpi.com/2072-666X/9/7/332</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/mi9070332" target="_blank" >10.3390/mi9070332</a>

Result language

angličtina

Original language name

Development of Porous Coatings Enriched with Magnesium and Zinc Obtained by DC Plasma Electrolytic Oxidation

Original language description

Coatings with developed surface stereometry, being based on a porous system, may be obtained by plasma electrolytic oxidation, PEO (micro arc oxidation, MAO). In this paper, we present novel porous coatings, which may be used, e.g., in micromachine&apos;s biocompatible sensors&apos; housing, obtained in electrolytes containing magnesium nitrate hexahydrate Mg(NO3)(2)center dot 6H(2)O and/or zinc nitrate hexahydrate Zn(NO3)(2)center dot 6H(2)O in concentrated phosphoric acid H3PO4 (85% w/w). Complementary techniques are used for coatings&apos; surface characterization, such as scanning electron microscopy (SEM), for surface imaging as well as for chemical semi-quantitative analysis via energy dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), glow discharge optical emission spectroscopy (GDOES), and X-ray powder diffraction (XRD). The results have shown that increasing contents of salts (here, 250 g/L Mg(NO3)(2)center dot 6H(2)O and 250 g/L Zn(NO3)(2)center dot 6H(2)O) in electrolyte result in increasing of Mg/P and Zn/P ratios, as well as coating thickness. It was also found that by increasing the PEO voltage, the Zn/P and Mg/P ratios increase as well. In addition, the analysis of XPS spectra revealed the existence in 10 nm top of coating magnesium (Mg2+), zinc (Zn2+), titanium (Ti4+), and phosphorus compounds (PO43-, or HPO42-, or H2PO4-, or P2O74-).

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

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OECD FORD branch

10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Project

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Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2018

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Micromachines

ISSN

2072-666X

e-ISSN

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Volume of the periodical

9

Issue of the periodical within the volume

7

Country of publishing house

CH - SWITZERLAND

Number of pages

19

Pages from-to

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UT code for WoS article

000441156000020

EID of the result in the Scopus database

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