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Insights into 1-butyl-3-methylimidazolium hydrogen sulfate recovery from wastewater by electrodialysis with heterogeneous ion-exchange membranes

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27350%2F25%3A10257770" target="_blank" >RIV/61989100:27350/25:10257770 - isvavai.cz</a>

  • Result on the web

    <a href="https://www.nature.com/articles/s41598-025-04108-y" target="_blank" >https://www.nature.com/articles/s41598-025-04108-y</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1038/s41598-025-04108-y" target="_blank" >10.1038/s41598-025-04108-y</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Insights into 1-butyl-3-methylimidazolium hydrogen sulfate recovery from wastewater by electrodialysis with heterogeneous ion-exchange membranes

  • Original language description

    Due to the negative impact of ionic liquids (ILs) on the environment and their high cost, it is very important to examine their recovery and recycling methods. Thus, in this study, research on 1-butyl-3-methylimidazolium hydrogen sulfate ([Bmim]HSO&lt;inf&gt;4&lt;/inf&gt;) recovery from wastewater by electrodialysis (ED) is presented. The influence of the initial [Bmim]HSO&lt;inf&gt;4&lt;/inf&gt; concentration, the voltage, and the linear flow velocity on the effective [Bmim]HSO&lt;inf&gt;4&lt;/inf&gt; recovery was examined. To assess the effectiveness of the proposed method, factors such as IL percentage recovery, degree of concentration, electric current efficiency, and energy consumption were determined. It was found that as the initial concentration of [Bmim]HSO&lt;inf&gt;4&lt;/inf&gt; in the feed solution increased from 0.01 to 0.2 M, the [Bmim]HSO&lt;inf&gt;4&lt;/inf&gt; recovery efficiency increased. A 2.3-fold concentration of the [Bmim]HSO&lt;inf&gt;4&lt;/inf&gt; in the concentrate solution with a recovery of 98.8%, a current efficiency of 67.3%, and energy consumption of 28 kWh/m&lt;sup&gt;3&lt;/sup&gt; was achieved for ED of a 0.2 M [Bmim]HSO&lt;inf&gt;4&lt;/inf&gt; solution using heterogeneous ion-exchange membranes. Additionally, the voltage and linear flow velocity affected the [Bmim]HSO&lt;inf&gt;4&lt;/inf&gt; recovery. The highest ED efficiency for the recovery and concentration of [Bmim]HSO&lt;inf&gt;4&lt;/inf&gt; was obtained at an applied potential of 4 V, a 2 cm/s linear flow velocity, and 0.2 M IL in the feed solution.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20400 - Chemical engineering

Result continuities

  • Project

  • Continuities

    O - Projekt operacniho programu

Others

  • Publication year

    2025

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Scientific Reports

  • ISSN

    2045-2322

  • e-ISSN

    2045-2322

  • Volume of the periodical

    15

  • Issue of the periodical within the volume

    15

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    17

  • Pages from-to

    nestránkováno

  • UT code for WoS article

    001501594000022

  • EID of the result in the Scopus database

    2-s2.0-105006996053