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Protonation of methylene blue and its intercalation into montmorillonite.

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27360%2F09%3A00022145" target="_blank" >RIV/61989100:27360/09:00022145 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Protonation of methylene blue and its intercalation into montmorillonite.

  • Original language description

    The protonation of methylene blue (MB) was studied in variously acid aqueous solutions using Vis spectrophotometry. The cations of MB present in acid aqueous solutions, i.e. MB+, (MB+)n and MBH2+, were intercalated into Ca-montmorillonite (SAz-1). Adsorbed amounts of dye were evaluated by Vis spectrophotometry at two wavelengths; at 675 nm (monomeric form MB+) and at 748 nm (protonated form MBH2+). By this way two independent measurements of equilibrium dye concentration in acid aqueous solutions were obtained and used for the evaluation of the adsorbed amount of methylene blue into SAz-1. Adsorption curves determined in acid aqueous solutions consist of two separated steps whereas the adsorption curve determined in neutral aqueous solution has only one step. Intercalated MB/SAz-1 samples were studied using X-ray powder diffraction method and SEM. It was found that the first step of adsorption curve relates to ion exchange of MB cations with interlayer Ca2+ cations and the second one r

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA205%2F08%2F0869" target="_blank" >GA205/08/0869: Clay minerals as host matrices for functional nanostructures</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2009

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    International doctoral seminar

  • ISBN

    978-80-8096-088-9

  • ISSN

  • e-ISSN

  • Number of pages

    5

  • Pages from-to

  • Publisher name

    Slovenská technická univerzita v Bratislavě

  • Place of publication

    Bratislava

  • Event location

    Smolenice

  • Event date

    May 17, 2009

  • Type of event by nationality

    EUR - Evropská akce

  • UT code for WoS article