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N2O catalytic decomposition ? from laboratory experiment to industry reactor

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27360%2F12%3A86083728" target="_blank" >RIV/61989100:27360/12:86083728 - isvavai.cz</a>

  • Alternative codes found

    RIV/67985858:_____/12:00398556

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.cattod.2012.03.045" target="_blank" >http://dx.doi.org/10.1016/j.cattod.2012.03.045</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.cattod.2012.03.045" target="_blank" >10.1016/j.cattod.2012.03.045</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    N2O catalytic decomposition ? from laboratory experiment to industry reactor

  • Original language description

    Paper deals with design of pilot reactor for low temperature N2O decomposition in off-gases from HNO3 production. Pseudo-homogeneous one-dimensional model of an ideal plug flow reactor was used for modeling of N2O decomposition in a laboratory fixed bedreactor filled with grains or pellets of a Co-Mn-Al mixed oxide catalyst. Increase in inlet pressure up to 0.6 MPa did not influence the effective diffusion coefficient, but improved the achieved N2O conversion. Based on the laboratory data of N2O decomposition over Co-Mn-Al mixed oxide pellets, catalyst bed of 3400 kg was estimated for target 90 % N2O conversion (30 000 m3 h-1 of exhaust gases from HNO3 plant containing 0.1 molar% N2O, 0.01 molar% NO, 0.01 molar% NO2, 3 molar% H2O, 5 molar% O2) at 420°C and 600 kPa inlet pressure.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CI - Industrial chemistry and chemical engineering

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/TA01020336" target="_blank" >TA01020336: Abatement of N2O emissions from waste gas of nitric acid production</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2012

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Catalysis Today

  • ISSN

    0920-5861

  • e-ISSN

  • Volume of the periodical

    191

  • Issue of the periodical within the volume

    1

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    5

  • Pages from-to

    116-120

  • UT code for WoS article

    000308675000020

  • EID of the result in the Scopus database