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Effects of Eu3+ ions doping on physicochemical properties of spinel-structured lithium-titanium oxide (Li4Ti5O12) as an efficient photoluminescent material

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27360%2F21%3A10247157" target="_blank" >RIV/61989100:27360/21:10247157 - isvavai.cz</a>

  • Result on the web

    <a href="https://www.sciencedirect.com/science/article/pii/S0025540820315658?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0025540820315658?via%3Dihub</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.materresbull.2020.111084" target="_blank" >10.1016/j.materresbull.2020.111084</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Effects of Eu3+ ions doping on physicochemical properties of spinel-structured lithium-titanium oxide (Li4Ti5O12) as an efficient photoluminescent material

  • Original language description

    In this work we report our recent efforts on the investigation of the compositional and structural features of series of nanocrystalline Li4Ti5O12 (LTO) doped with Eu3+ ions powders, which were synthesized in a high-energy ballmilling (HEBM) process. Lithium carbonate, titanium and europium oxides were used as starting reagents. The ball-milled materials were turned into nanocrystalline powders due to the heating that was carried out in the air in the temperature range from 500 to 800 degrees C. The synthesized LTO doped with Eu3+ powders were examined by a number of physicochemical techniques: X-ray powder diffraction (XRD), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), Fourier-transform infrared spectroscopy (FTIR), absorption and emission spectroscopy (photoluminescence and excitation spectra were recorded), diffuse reflection spectroscopy (UV-vis DRS), scanning electron (SEM), transmission (TEM) and atomic force (AFM) microscopy. Structural, morphological and photoluminescent properties were correlated and examined for the first time in this work. The obtained results suggest that LTO material doped with rare earth ions like europium could serve as a material for applications in optoelectmnic devices such as white light emitting diodes (WLEDs).

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10400 - Chemical sciences

Result continuities

  • Project

  • Continuities

    O - Projekt operacniho programu

Others

  • Publication year

    2021

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Materials Research Bulletin

  • ISSN

    0025-5408

  • e-ISSN

  • Volume of the periodical

    134

  • Issue of the periodical within the volume

    February 2021

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    10

  • Pages from-to

  • UT code for WoS article

    000600378400004

  • EID of the result in the Scopus database

    2-s2.0-85092100356