Uncovering the Role of Trioctylphosphine on Colloidal and Emission Stability of Sb-Alloyed Cs2NaInCl6 Double Perovskite Nanocrystals
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27640%2F21%3A10248949" target="_blank" >RIV/61989100:27640/21:10248949 - isvavai.cz</a>
Alternative codes found
RIV/61989592:15640/21:73610977
Result on the web
<a href="https://pubs.acs.org/doi/pdf/10.1021/acsami.1c10782" target="_blank" >https://pubs.acs.org/doi/pdf/10.1021/acsami.1c10782</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acsami.1c10782" target="_blank" >10.1021/acsami.1c10782</a>
Alternative languages
Result language
angličtina
Original language name
Uncovering the Role of Trioctylphosphine on Colloidal and Emission Stability of Sb-Alloyed Cs2NaInCl6 Double Perovskite Nanocrystals
Original language description
Doping and compositional tuning of Cs(2)AInCl(6) (A = Ag, Na) double perovskite nanocrystals (PNCs) is considered a promising strategy toward the development of light-emitting sources for applications in solution-processed optoelectronic devices. Oleic acid and oleylamine are by far the most often used surface capping ligands for PNCs. However, the undesirable desorption of these ligands due to proton-exchange reaction during isolation and purification processing results in colloidal and structural instabilities. Thus, the improvement of colloidal and optical stability of PNCs represents one of the greatest challenges in the field. Here, we report a trioctylphosphine-mediated synthesis and purification method toward Sb-alloyed Cs2NaInCl6 PNCs with excellent stability and optical features. Nuclear magnetic resonance spectroscopy enabled one to explain the role of trioctylphosphine and to reveal the reaction mechanism during crystal nucleation and growth. Under the optimized reaction conditions, in situ-generated trioctylphosphonium chloride and benzoyl trioctylphosphonium chloride serve as highly reactive halide sources, while benzoyl trioctylphosphonium and oleylammonium cations together with the oleate anion serve as surface capping ligands, which are bound strongly to the PNC surface. The tightly bound ionic pair of oleylammonium oleate and benzoyl trioctylphosphonium chloride/oleate ligands allows one to obtain monodispersed bright-blue-emitting PNCs with high photoluminescence quantum yields exceeding 50% at an optimum Sb content (0.5%), which also exhibit long-term colloidal stability. The approach based on dual cationic ligand passivation of double PNCs opens the doors for applications in other systems with a potential to achieve higher stability along with superior optical properties.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
21000 - Nano-technology
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ACS applied materials & interfaces
ISSN
1944-8244
e-ISSN
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Volume of the periodical
13
Issue of the periodical within the volume
40
Country of publishing house
US - UNITED STATES
Number of pages
15
Pages from-to
47845-47859
UT code for WoS article
000709458200051
EID of the result in the Scopus database
2-s2.0-85117307104