Single-Atom (Iron-Based) Catalysts: Synthesis and Applications
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27640%2F21%3A10248976" target="_blank" >RIV/61989100:27640/21:10248976 - isvavai.cz</a>
Alternative codes found
RIV/61989592:15640/21:73611247
Result on the web
<a href="https://pubs.acs.org/doi/pdf/10.1021/acs.chemrev.1c00158" target="_blank" >https://pubs.acs.org/doi/pdf/10.1021/acs.chemrev.1c00158</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.chemrev.1c00158" target="_blank" >10.1021/acs.chemrev.1c00158</a>
Alternative languages
Result language
angličtina
Original language name
Single-Atom (Iron-Based) Catalysts: Synthesis and Applications
Original language description
Supported single-metal atom catalysts (SACs) are constituted of isolated active metal centers, which are heterogenized on inert supports such as graphene, porous carbon, and metal oxides. Their thermal stability, electronic properties, and catalytic activities can be controlled via interactions between the single-metal atom center and neighboring heteroatoms such as nitrogen, oxygen, and sulfur. Due to the atomic dispersion of the active catalytic centers, the amount of metal required for catalysis can be decreased, thus offering new possibilities to control the selectivity of a given transformation as well as to improve catalyst turnover frequencies and turnover numbers. This review aims to comprehensively summarize the synthesis of Fe-SACs with a focus on anchoring single atoms (SA) on carbon/graphene supports. The characterization of these advanced materials using various spectroscopic techniques and their applications in diverse research areas are described. When applicable, mechanistic investigations conducted to understand the specific behavior of Fe-SACs-based catalysts are highlighted, including the use of theoretical models.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10400 - Chemical sciences
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemical Reviews
ISSN
0009-2665
e-ISSN
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Volume of the periodical
121
Issue of the periodical within the volume
21
Country of publishing house
US - UNITED STATES
Number of pages
78
Pages from-to
13620-13697
UT code for WoS article
000718326200010
EID of the result in the Scopus database
2-s2.0-85118274935