Graphene Acid for Lithium-Ion Batteries-Carboxylation Boosts Storage Capacity in Graphene
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27640%2F22%3A10248946" target="_blank" >RIV/61989100:27640/22:10248946 - isvavai.cz</a>
Alternative codes found
RIV/61989592:15310/21:73610454 RIV/61989592:15640/21:73610454 RIV/61989100:27740/22:10248946
Result on the web
<a href="https://onlinelibrary.wiley.com/doi/epdf/10.1002/aenm.202103010" target="_blank" >https://onlinelibrary.wiley.com/doi/epdf/10.1002/aenm.202103010</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/aenm.202103010" target="_blank" >10.1002/aenm.202103010</a>
Alternative languages
Result language
angličtina
Original language name
Graphene Acid for Lithium-Ion Batteries-Carboxylation Boosts Storage Capacity in Graphene
Original language description
Environmentally sustainable, low-cost, flexible, and lightweight energy storage technologies require advancement in materials design in order to obtain more efficient organic metal-ion batteries. Synthetically tailored organic molecules, which react reversibly with lithium, may address the need for cost-effective and eco-friendly anodes used for organic/lithium battery technologies. Among them, carboxylic group-bearing molecules act as high-energy content anodes. Although organic molecules offer rich chemistry, allowing a high content of carboxyl groups to be installed on aromatic rings, they suffer from low conductivity and leakage to the electrolytes, which restricts their actual capacity, the charging/discharging rate, and eventually their application potential. Here, a densely carboxylated but conducting graphene derivative (graphene acid (GA)) is designed to circumvent these critical limitations, enabling effective operation without compromising the mechanical or chemical stability of the electrode. Experiments including operando Raman measurements and theoretical calculations reveal the excellent charge transport, redox activity, and lithium intercalation properties of the GA anode at the single-layer level, outperforming all reported organic anodes, including commercial monolayer graphene and graphene nanoplatelets. The practical capacity and rate capability of 800 mAh g(-1) at 0.05 A g(-1) and 174 mAh g(-1) at 2.0 A g(-1) demonstrate the true potential of GA anodes in advanced lithium-ion batteries.
Czech name
—
Czech description
—
Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
21100 - Other engineering and technologies
Result continuities
Project
<a href="/en/project/GX19-27454X" target="_blank" >GX19-27454X: Control of electronic properties of metal-containing molecules through their noncovalent interactions with solvents, ligands and 2D nanosystems</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Advanced Energy Materials
ISSN
1614-6832
e-ISSN
1614-6840
Volume of the periodical
12
Issue of the periodical within the volume
5
Country of publishing house
DE - GERMANY
Number of pages
11
Pages from-to
nestrankovano
UT code for WoS article
000732712200001
EID of the result in the Scopus database
2-s2.0-85121572048