Ni-Based Nanoparticles Catalyzed Hydrodeoxygenation of Ketones, Ethers, and Phenols to (Cyclo) Aliphatic Compounds
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27640%2F23%3A10253205" target="_blank" >RIV/61989100:27640/23:10253205 - isvavai.cz</a>
Result on the web
<a href="https://pubs.acs.org/doi/epdf/10.1021/acssuschemeng.3c03661" target="_blank" >https://pubs.acs.org/doi/epdf/10.1021/acssuschemeng.3c03661</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acssuschemeng.3c03661" target="_blank" >10.1021/acssuschemeng.3c03661</a>
Alternative languages
Result language
angličtina
Original language name
Ni-Based Nanoparticles Catalyzed Hydrodeoxygenation of Ketones, Ethers, and Phenols to (Cyclo) Aliphatic Compounds
Original language description
Catalytic hydrodeoxygenation is of prime importance in the valorization of biomass-based feedstocks to produce essential chemicals and fuels. To carry out this process in a more cost-effective and sustainable manner, the use of 3D-metal-based nanostructured catalysts is highly desired. Here, we report the preparation and application of Ni nanoparticles supported on ZSM-5 (the Si/Al ratio is 80) as a general and efficient hydrodeoxygenation catalyst. These Ni-based nanoparticles catalyze the selective hydrodeoxygenation of a wide range of funcational substrates, including ketones, ethers, and phenols, and also reduce aromatic rings to produce (cyclo) alkanes. Notably, the hydrodeoxygenation of fatty acid derived ketones to long-chain alkanes, lignin derived molecules, and polyether ether ketone decomposition compounds to cyclohexane-based products highlight the versatility of this novel Ni catalyst. (C) 2023 American Chemical Society.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
21000 - Nano-technology
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2023
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ACS Sustainable Chemistry and Engineering
ISSN
2168-0485
e-ISSN
2168-0485
Volume of the periodical
11
Issue of the periodical within the volume
42
Country of publishing house
US - UNITED STATES
Number of pages
13
Pages from-to
15302-15314
UT code for WoS article
001076150500001
EID of the result in the Scopus database
2-s2.0-85174919549