A Cobalt Nanocatalyst for the Hydrogenation and Oxidative Dehydrogenation of N-heterocycles

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27640%2F23%3A10253958" target="_blank" >RIV/61989100:27640/23:10253958 - isvavai.cz</a>

Result on the web

<a href="https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/cctc.202301027" target="_blank" >https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/cctc.202301027</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/cctc.202301027" target="_blank" >10.1002/cctc.202301027</a>

Result language

angličtina

Original language name

A Cobalt Nanocatalyst for the Hydrogenation and Oxidative Dehydrogenation of N-heterocycles

Original language description

Catalytic hydrogenation and oxidative dehydrogenation of N-heterocycles to produce tetrahydroquinoline and quinoline derivatives are important reactions of particular importance in the agrochemical and pharmaceutical industries. Herein, we report earth-abundant cobalt nanoparticles supported on hydroxyapatite (HAP) as an inexpensive and efficient catalyst for the hydrogenation and reverse oxidative dehydrogenation of N-heterocycles. The optimal nanocatalyst exhibits excellent activity in both reactions for a wide range of substrates including (iso)quinolines, acridine, benzo[h]quinoline, quinoxaline and indole. Reactions proceed under relatively mild conditions without requiring any additives. Non-noble catalyst for hydrogenation and oxidative dehydrogenation of N-heterocycles process: Pyrolysis of Co-PZ-TPA supported on hydroxyapatite resulting in an active and reusable core-shell nanocatalyst with high activity in hydrogenation and its reversible oxidative dehydrogenation of N-heterocycles.image

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

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OECD FORD branch

10400 - Chemical sciences

Project

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Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2023

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

ChemCatChem

ISSN

1867-3880

e-ISSN

1867-3899

Volume of the periodical

16

Issue of the periodical within the volume

1

Country of publishing house

DE - GERMANY

Number of pages

9

Pages from-to

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UT code for WoS article

001096392100001

EID of the result in the Scopus database

2-s2.0-85175633238