Deciphering the Role of Nickel in Electrochemical Organic Oxidation Reactions
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27640%2F24%3A10255074" target="_blank" >RIV/61989100:27640/24:10255074 - isvavai.cz</a>
Result on the web
<a href="https://onlinelibrary.wiley.com/doi/epdf/10.1002/aenm.202400696" target="_blank" >https://onlinelibrary.wiley.com/doi/epdf/10.1002/aenm.202400696</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/aenm.202400696" target="_blank" >10.1002/aenm.202400696</a>
Alternative languages
Result language
angličtina
Original language name
Deciphering the Role of Nickel in Electrochemical Organic Oxidation Reactions
Original language description
Organic oxidation reactions (OORs) powered by renewable energy sources are gaining importance as a favorable alternative to oxygen evolution reaction, with the promise of reducing the cell potential and enhancing the overall viability of the water electrolysis. This comprehensive review delves into the electrochemical oxidation of diverse organic compounds, including alcohols, aldehydes, amines, and urea, as well as biomass-derived renewable feedstocks such as hydroxymethylfurfural and glycerol. The key focus centers on the role of nickel (Ni)-based catalysts for these OORs. The unique redox activity and chemical nature of Ni have been proven instrumental for the sustainable and cost-effective oxidation of various organic molecules more efficiently and selectively. This review article discusses how strategic choices, such as the selection of foreign metals, intercalating species, vacancies, defects, and a secondary element (e.g. chalcogens and non-metals), contribute to tuning the electrochemical performances of a Ni-based (pre)catalyst for OORs. Moreover, this review provides insights into the active species in various reaction environments and further explores reaction mechanisms, to apparent phase changes of the catalyst with the most relevant examples. Finally, the review not only elucidates the limitations of the current approaches but also outlines potential avenues for future advancements in OOR. (C) 2024 The Authors. Advanced Energy Materials published by Wiley-VCH GmbH.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10400 - Chemical sciences
Result continuities
Project
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Continuities
O - Projekt operacniho programu
Others
Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Advanced Energy Materials
ISSN
1614-6832
e-ISSN
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Volume of the periodical
14
Issue of the periodical within the volume
22
Country of publishing house
DE - GERMANY
Number of pages
24
Pages from-to
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UT code for WoS article
001198172300001
EID of the result in the Scopus database
2-s2.0-85189645532