Reusable Co-catalysts for general and selective α-alkylation of nitriles with alcohols
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27640%2F24%3A10256558" target="_blank" >RIV/61989100:27640/24:10256558 - isvavai.cz</a>
Result on the web
<a href="https://pubs.rsc.org/en/content/articlelanding/2024/gc/d3gc04436j" target="_blank" >https://pubs.rsc.org/en/content/articlelanding/2024/gc/d3gc04436j</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/d3gc04436j" target="_blank" >10.1039/d3gc04436j</a>
Alternative languages
Result language
angličtina
Original language name
Reusable Co-catalysts for general and selective α-alkylation of nitriles with alcohols
Original language description
A general cobalt-catalyzed alpha-alkylation of nitriles with alcohols is reported. Utilizing this straightforward borrowing hydrogen methodology, a series of substituted and functionalized nitriles can be easily coupled with benzylic, heterocyclic, and aliphatic alcohols to prepare diverse functionalized nitriles in good to excellent yields (>70 examples). Key for this synthesis is the use of specific cobalt-nanoparticles supported on N-doped carbon, which were conveniently prepared by pyrolysis of a templated material generated in situ by mixing cobalt chloride, zinc chloride, d-glucosamine hydrochloride, and colloidal silica, and subsequent removal of the silica.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10400 - Chemical sciences
Result continuities
Project
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Continuities
O - Projekt operacniho programu
Others
Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Green Chemistry
ISSN
1463-9262
e-ISSN
1463-9270
Volume of the periodical
26
Issue of the periodical within the volume
Nov
Country of publishing house
GB - UNITED KINGDOM
Number of pages
7
Pages from-to
11140-11146
UT code for WoS article
001344724400001
EID of the result in the Scopus database
2-s2.0-85208599248