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Hydrogen production from microwave catalytic pyrolysis of spruce sawdust

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27710%2F17%3A10237365" target="_blank" >RIV/61989100:27710/17:10237365 - isvavai.cz</a>

  • Result on the web

    <a href="https://www.sciencedirect.com/science/article/pii/S0165237016308476?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0165237016308476?via%3Dihub</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.jaap.2017.02.008" target="_blank" >10.1016/j.jaap.2017.02.008</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Hydrogen production from microwave catalytic pyrolysis of spruce sawdust

  • Original language description

    The production of energy from wood biomass is as old as humanity itself. In the last 20 years there has been enormous progress in research of torrefaction, pyrolysis and mainly gasification of biomass. Products from conventional pyrolysis of biomass are gas known as pyrolysis gas, a liquid condensate known as bio-oil and char named bio-char. Most of the articles dealing with convectional pyrolysis of biomass are focused on the production of bio-oil. Only some works deal with the possibility of producing high-quality syngas (H2 +CO) or hydrogen itself. For this purpose, the technology of microwave pyrolysis could be suitable. Microwaves can generate microplasma and hot spots, which promote heterogeneous catalytic reactions and produce a greater concentration of hydrogen in the resulting gas than convectional pyrolysis. In this work, an experimental study of spruce sawdust microwave pyrolysis was performed in the presence of catalysts to maximize the yield of hydrogen or syngas. Experiments were carried out in a microwave reactor with a power of 400W. As catalysts char from sawdust, or sawdust char-doped with metal ions (Ni, Co, Fe) were used. Ions of metals were used to increase the yield of hydrogen (e.g. Nickel is widely used in the catalytic cracking of methane). The influence of the catalyst on the quantity of products (gas, liquid and solid) was studied, as well as the amount of hydrogen generated in the pyrolysis gas, or the amount of waste water in the liquid condensate. © 2017 Elsevier B.V.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20402 - Chemical process engineering

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2017

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Analytical and Applied Pyrolysis

  • ISSN

    0165-2370

  • e-ISSN

  • Volume of the periodical

    124

  • Issue of the periodical within the volume

    March

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    5

  • Pages from-to

    175-179

  • UT code for WoS article

    000399624500018

  • EID of the result in the Scopus database