Broadband Mueller ellipsometer as an all-in-one tool for spectral and temporal analysis of mutarotation kinetics

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27730%2F23%3A10251826" target="_blank" >RIV/61989100:27730/23:10251826 - isvavai.cz</a>

Alternative codes found

RIV/61989100:27360/23:10251826 RIV/61989100:27740/23:10251826

Result on the web

<a href="https://pubs.rsc.org/en/content/articlelanding/2023/RA/D3RA00101F" target="_blank" >https://pubs.rsc.org/en/content/articlelanding/2023/RA/D3RA00101F</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/d3ra00101f" target="_blank" >10.1039/d3ra00101f</a>

Result language

angličtina

Original language name

Broadband Mueller ellipsometer as an all-in-one tool for spectral and temporal analysis of mutarotation kinetics

Original language description

Spectroscopic Mueller matrix ellipsometry is becoming increasingly routine across physical branches ofscience, even outside optics. The highly sensitive tracking of the polarization-related physical propertiesoffers a reliable and non-destructive analysis of virtually any sample at hand. If coupled with a physicalmodel, it is impeccable in performance and irreplaceable in versatility. Nonetheless, this method is rarelyadopted interdisciplinarily, and when it is, it often plays a supporting role, which does not take benefit ofits full potential. To bridge this gap, we present Mueller matrix ellipsometry in the context of chiropticalspectroscopy. In this work, we utilize a commercial broadband Mueller ellipsometer to analyze theoptical activity of a saccharides solution. We verify the correctness of the method in the first place bystudying the well-known rotatory power of glucose, fructose, and sucrose. By employing a physicallymeaningful dispersion model, we obtain 2p-unwrapped absolute specific rotations. Besides that, wedemonstrate the capability of tracing the glucose mutarotation kinetics from just one set ofmeasurements. Coupling the Mueller matrix ellipsometry with the proposed dispersion model ultimatelyleads to the precisely determined mutarotation rate constants and spectrally and temporally resolvedgyration tensor of individual glucose anomers. In this view, Mueller matrix ellipsometry may stand as anoffbeat yet equal technique to those considered classical chiroptical spectroscopy techniques, whichmay help open new opportunities for broader polarimetric applications in biomedicine and chemistry.

Czech name

—

Czech description

—

Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

—

OECD FORD branch

10300 - Physical sciences

Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2023

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

RSC Advances

ISSN

2046-2069

e-ISSN

—

Volume of the periodical

13

Issue of the periodical within the volume

10

Country of publishing house

GB - UNITED KINGDOM

Number of pages

11

Pages from-to

6582-6592

UT code for WoS article

000939685500001

EID of the result in the Scopus database

2-s2.0-85149663593