Metal complexes as anticancer agent 2. Iron(III) and copper(II) bio-active complexes with benzylaminopurine derivatives.

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F01%3A00001345" target="_blank" >RIV/61989592:15310/01:00001345 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Metal complexes as anticancer agent 2. Iron(III) and copper(II) bio-active complexes with benzylaminopurine derivatives.
Original language description
Iron(III) complexes with 2-(3-hydroxypropylamino )-6-benzylamino-9-isopropylpurine (Bohemin, HL1), in its protonized form, of the composition (H+HL1)2[FeCl5] # 2H2O (1), (H+HL1)2[FeCl5] # 3H2O (2) have been prepared by two different routes. A new way forsynthesis of copper(II) complex with 6-(2-ch1orobenzylarnino)purine (HL2), [Cu2(#-Cl)2(#-HL2)2(HL2)2Cl2] # 2H2O (3), together with the preparation of copper(II) complex with 6-(3-chlorobenzylarnino)purine (HL3), [Cu2(#-Cl)2(#-HL3)2Cl2] (4), is also reported. The characterization have been based on elemental analysis, electronic, infrared, ES + mass and 57Fe Mössbauer spectra, conductivity data and magnetic susceptibility temperature measurements over the 4.5-300 K for 1-3, and 35-300 K for 4, temperature range, respectively .Molecular structure of an electroneutral form of the HL3 ligand, (HL2 # 2H2O), and a protonized form of the HL3 ligand, (H+HL3-Cl), have been determined by a single-crystal X-ray analysis. A mononuclear trigonal-bi
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
ED - Physiology
OECD FORD branch
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Publication year
2001
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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