Syntheses and structure of Ni(III) complexes with 1-toluene 3,4-dithiole. Bond-valence approach to the oxidation state of the central atom

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F02%3A00001531" target="_blank" >RIV/61989592:15310/02:00001531 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Syntheses and structure of Ni(III) complexes with 1-toluene 3,4-dithiole. Bond-valence approach to the oxidation state of the central atom

Original language description

The complex compounds of the formula (R)[Ni-III(tdt)(2)], R = Met(4)N (I), Et4N (II), Pr4N (III), MePh3P (IV), Ph4P (V); tdt = 1-toluene-3,4-dithiole have been synthesized. The crystal structures of the compounds III and IV were determined by X-rays studies. Bond valence as a function of inter-nuclear distance for Ni-S bonds was estimated. On the basis of physico-chemical measurements and bond-valence sum model, the formal oxidation state III of Ni atoms for both structures was proposed.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2002

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Polish Journal of Chemistry

ISSN

0137-5083

e-ISSN

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Volume of the periodical

76

Issue of the periodical within the volume

4

Country of publishing house

PL - POLAND

Number of pages

8

Pages from-to

483-490

UT code for WoS article

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EID of the result in the Scopus database

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