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Syntheses and structure of Ni(III) complexes with 1-toluene 3,4-dithiole. Bond-valence approach to the oxidation state of the central atom

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F02%3A00001531" target="_blank" >RIV/61989592:15310/02:00001531 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Syntheses and structure of Ni(III) complexes with 1-toluene 3,4-dithiole. Bond-valence approach to the oxidation state of the central atom

  • Original language description

    The complex compounds of the formula (R)[Ni-III(tdt)(2)], R = Met(4)N (I), Et4N (II), Pr4N (III), MePh3P (IV), Ph4P (V); tdt = 1-toluene-3,4-dithiole have been synthesized. The crystal structures of the compounds III and IV were determined by X-rays studies. Bond valence as a function of inter-nuclear distance for Ni-S bonds was estimated. On the basis of physico-chemical measurements and bond-valence sum model, the formal oxidation state III of Ni atoms for both structures was proposed.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2002

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Polish Journal of Chemistry

  • ISSN

    0137-5083

  • e-ISSN

  • Volume of the periodical

    76

  • Issue of the periodical within the volume

    4

  • Country of publishing house

    PL - POLAND

  • Number of pages

    8

  • Pages from-to

    483-490

  • UT code for WoS article

  • EID of the result in the Scopus database