Non-Symmetrical Nickel(II)dithiocarbamates with NiS2P2-Chromophore
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F02%3A00001599" target="_blank" >RIV/61989592:15310/02:00001599 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Non-Symmetrical Nickel(II)dithiocarbamates with NiS2P2-Chromophore
Original language description
Non-sym. substituted Ni(II)dithiocarbamate complexes with NiS2P2 chromophore of compn. [Ni(bziprdtc)(PPh3)2]X, [Ni(bziprdtc)(PPh3)2]BPh4#3H2O (bziprdtc- = benzylisopropyldithiocarbamate, PPh3 = triphenylphosphine, BPh4- = tetraphenylborate, X = ClO4-, PF6-), [Ni(cetdtc)(PPh3)2]X, [Ni(cetdtc)(PPh3)2]PF6, [Ni(cetdtc)(PBut3)2]X (cetdtc- = cyclohexylethyldithiocarbamate, PBut3 = tributylphosphine, X = ClO4-, BPh4-) have been isolated. These complexes have been characterized by elemental anal., IR and UV-VISspectroscopy, thermal anal., magnetochem. and cond. measurements. X-ray structural anal. of [Ni(bziprdtc)(PPh3)2]ClO4#0.5H2O confirms the NiS2P2 chromophore with a slightly distorted square arrangement around the central atom.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2002
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Polish Journal of Chemistry
ISSN
0137-5083
e-ISSN
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Volume of the periodical
76
Issue of the periodical within the volume
11
Country of publishing house
PL - POLAND
Number of pages
7
Pages from-to
1545-1551
UT code for WoS article
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EID of the result in the Scopus database
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