Ni(II) complexes of unsymmetrical phenyl and phenethyl dithiocarbamates and triphenylphosphine

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F06%3A00002748" target="_blank" >RIV/61989592:15310/06:00002748 - isvavai.cz</a>

Alternative codes found

RIV/61988987:17310/06:A0900G5E

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Ni(II) complexes of unsymmetrical phenyl and phenethyl dithiocarbamates and triphenylphosphine

Original language description

Unsymmetrical Ni(II) complexes of phenyl- and phenethyldithiocarbamate nad PPh3 of composition [NiX(HPhdtc)(PPh3)], [NiX(HPhetdc)(PPh3)], [Ni(HPhdtc)(PPh3)(2)]ClO4 and [Ni(HPhdtc)(PPh3)(2)]PF6 {X = Cl, Br, I, NCS; HPhdtc = phenyldithiocarbamate, HPhentdtc = phenethyldithiocarbamate, PPh3 = triphenylphosphine} have been synthesized. The complexes have been characterized by elemental and thermal analysis, IR and electronic spectroscopy, magnetochemical and conductivity measurements. Single-crystal X-ray analysis of [NiBr(HPhdtc)(PPh3)].CHCl3 confirmed a distorted square planar coordination for the NiS2PBr chromophore. For selected samples, the catalytic effects of graphite oxidation were studied.

Czech name

Nikelnaté komplexy s nesymetrickými fenyl- a fenethyldithiokarbamaty a trifenylfosfinem

Czech description

Nesymetrické nikelnaté komplexy s fenyl- a fenethyldithiokarbamaty nad PPh3 o složení [NiX(HPhdtc)(PPh3)], [NiX(HPhetdc)(PPh3)], [Ni(HPhdtc)(PPh3)(2)]ClO4 a [Ni(HPhdtc)(PPh3)(2)]PF6 {X = Cl, Br, I, NCS; HPhdtc = fenyldithiokarbamat, HPhentdtc = fenethyldithiokarbamat, PPh3= trifenylfosfin} byly připraveny. Komplexy byly charakterizovány elementární a termickou analýzou, IR a elektronovou spektroskopií, magnetochemickým a vodivostním měřením. Monokrystalová rentgenostrukturní analýza[NiBr(HPhdtc)(PPh3)].CHCl3 potvrdila deformovanou čtvercovou koordinaci s NiS2PBr chromoforem. U vybraných vzorků byla studována katalytická aktivita při oxidaci grafitu.

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2006

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Coordination Chemistry

ISSN

0095-8972

e-ISSN

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Volume of the periodical

59

Issue of the periodical within the volume

4

Country of publishing house

GB - UNITED KINGDOM

Number of pages

8

Pages from-to

437-444

UT code for WoS article

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EID of the result in the Scopus database

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