6-(2-chlorobenzylamino)purinium tetra-chlorido(dimethyl sulfoxide-kappa O)(nitrosyl-kappa N)ruthenate(III) monohydrate
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F08%3A00005485" target="_blank" >RIV/61989592:15310/08:00005485 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
6-(2-chlorobenzylamino)purinium tetra-chlorido(dimethyl sulfoxide-kappa O)(nitrosyl-kappa N)ruthenate(III) monohydrate
Original language description
The asymmetric unit of the title complex salt, (C12H11ClN5)-[RuCl4(NO)(C2H6OS)]center dot H2O, contains a 6-(2-chlorobenzyl-amino) purinium cation, a tetrachlorido(dimethylsulfoxide)nitrosylruthenate(III) anion and one solvent water molecule. The Ru-IIIatom is octahedrally coordinated by four Cl atoms in the equatorial plane, and by a dimethyl sulfoxide O atom and a nitrosyl N atom in axial positions. The cation is an N3-protonated N7 tautomer. Intermolecular N-H center dot center dot center dot N hydrogen bonds connect two cations into centrosymmetric dimers, with an N center dot center dot center dot N distance of 2.821 (4) A. The crystal structure also involves N-H center dot center dot center dot O, N-H center dot center dot center dot Cl and O-Hcenter dot center dot center dot Cl hydrogen bonds.
Czech name
Tetrachloro-(dimethylsulfoxido-kappa O)(nitrosyl-kappa N)ruthenitan 6-(2-chlorbenzylamino)purinia monohydrát
Czech description
Byla studována struktura komplexní soli monohydrátu tetrarachloro-(dimethylsulfoxido-kappa O)(nitrosyl-kappa N)ruthenitanu 6-(2-chlorbenzylamino)purinia pomocí rentgenostrukturní analýzy.
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2008
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Acta Crystallographica Section E - Structure Reports Online
ISSN
1600-5368
e-ISSN
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Volume of the periodical
64
Issue of the periodical within the volume
4
Country of publishing house
DK - DENMARK
Number of pages
1
Pages from-to
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UT code for WoS article
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EID of the result in the Scopus database
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