Synthesis and Characterization of Linear Trinuclear Pd, Co, and Pd/Co Pyrazolate Complexes

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F08%3A00005525" target="_blank" >RIV/61989592:15310/08:00005525 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Synthesis and Characterization of Linear Trinuclear Pd, Co, and Pd/Co Pyrazolate Complexes

Original language description

A family of dinuclear and linear trinuclear Co/Pd pyrazolate compounds, namely, [Bu4N]2[Co2(-4-Cl-3,5-Me2-pz)2Cl4] (1), [Bu4N]2[Co2(-4-Br-3,5-Me2-pz)2Br4] (2), [Bu4N]2[Co2(4-I-3,5-Me2-pz)2Cl4] (3), [Et4N]2[Pd2Co(4-Br-3,5-Me2-pz)4Cl4] (4), [Et3NH]4[PdCo2(4-Br-3,5-Me2-pz)4Cl4][NO3]2 (5), [Et3NH]2[Pd Co2(3-Me-5-Ph-pz)4Cl4] (6), [Et3NH]2[Pd3(4-Br-3,5-Me2-pz)4Cl4] (7), and [Co3(3,5-Me2-pz)4(3,5-Me2-pzH)2(CH3CO2)2] (8) was synthesized. The single-phase nature of the solids was established by single-crystal X-ray diffraction, thermal analysis, and spectroscopic techniques. Moreover, the magnetic behavior is studied and a magnetostructural comparison to the corresponding carboxylate analogues is made.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2008

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

European Journal of Inorganic Chemistry

ISSN

1434-1948

e-ISSN

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Volume of the periodical

11

Issue of the periodical within the volume

30

Country of publishing house

DE - GERMANY

Number of pages

11

Pages from-to

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UT code for WoS article

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EID of the result in the Scopus database

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