Dinuclear Fe(III) complexes with spin crossover

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F09%3A00010180" target="_blank" >RIV/61989592:15310/09:00010180 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Dinuclear Fe(III) complexes with spin crossover

Original language description

A series of dinuclear Fe(III) complexes was synthesized in which the Schiff-base blocking ligand L-5 coordinates each of the centers which are linked by a bidentate, bipyridine-type ligand. For these systems, [(LFeIII)-Fe-5{bridge} (FeL5)-L-III](BPh4)(2), thermally induced spin crossover is observed. The corollary of the systems is that the spin crossover interferes with the magnetic exchange interaction. The overlap of the energy bands of the LL and HH reference states (L, low-spin; H, high-spin) causes the exchange interaction to act against the spin crossover (leading to incompleteness or gradual behavior).

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

<a href="/en/project/KAN115600801" target="_blank" >KAN115600801: New technologies of preparation and exploitation of iron oxide-based nanoparticles for environmental, industrial and medical applications</a><br>

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2009

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Monatshefte für Chemie

ISSN

0026-9247

e-ISSN

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Volume of the periodical

140

Issue of the periodical within the volume

7

Country of publishing house

DE - GERMANY

Number of pages

14

Pages from-to

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UT code for WoS article

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EID of the result in the Scopus database

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