Crystal Water Molecules as Magnetic Tuners in Molecular Metamagnets Exhibiting Antiferro-Ferro-Paramagnetic Transitions
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F11%3A33116852" target="_blank" >RIV/61989592:15310/11:33116852 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/ic201358c" target="_blank" >http://dx.doi.org/10.1021/ic201358c</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/ic201358c" target="_blank" >10.1021/ic201358c</a>
Alternative languages
Result language
angličtina
Original language name
Crystal Water Molecules as Magnetic Tuners in Molecular Metamagnets Exhibiting Antiferro-Ferro-Paramagnetic Transitions
Original language description
We studied the effects of the number of crystal water molecules on the magnetic behavior of {[Ni(en)2]3[Fe(CN)6]2.xH2O}n (1-3) (where en = ethylenediamine and x = 3, 2, or 0) coordination polymers by 57Fe Mossbauer spectroscopy, single-crystal X-ray diffraction, and magnetization measurements. Magnetic phase diagrams constructed for all three compounds indicate that they behave as metamagnets exhibiting very rare field-induced antiferro-ferro-paramagnetic transitions. The number of crystal water molecules has a major effect on the Neel temperature, critical field, and magnetic hardness of the compounds in the ferromagnetic state. Moreover, the systems behave as molecular magnetic sponges, changing their magnetic properties due to the controllable and reversible dehydration/hydration process.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Inorganic Chemistry
ISSN
0020-1669
e-ISSN
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Volume of the periodical
50
Issue of the periodical within the volume
18
Country of publishing house
US - UNITED STATES
Number of pages
11
Pages from-to
9153-9163
UT code for WoS article
000294699700054
EID of the result in the Scopus database
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