Tuning of spin crossover behaviour in iron(III) complexes involving pentadentate Schiff bases and pseudohalides
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F11%3A33116863" target="_blank" >RIV/61989592:15310/11:33116863 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1039/c1dt10696a" target="_blank" >http://dx.doi.org/10.1039/c1dt10696a</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c1dt10696a" target="_blank" >10.1039/c1dt10696a</a>
Alternative languages
Result language
angličtina
Original language name
Tuning of spin crossover behaviour in iron(III) complexes involving pentadentate Schiff bases and pseudohalides
Original language description
Eight mononuclear Fe(III) Schiff base complexes with the general formula [Fe(L5)(L1))].S (H2L5 = pentadentate Schiff-base ligand, L1 = a pseudohalido ligand, and S is a solvent molecule) are reported. Different aromatic 2-hydroxyaldehyde derivatives wereused in combination with a non-symmetrical triamine 1,6-diamino-4-azahexane to synthesize the H2L5 Schiff base ligands. The consecutive reaction with iron(III) chloride resulted in the preparation of the [Fe(L5)Cl] precursor complexes which were left toreact with a wide range of the L1 pseudohalido ligands. The low-spin compounds were prepared using the cyanido ligand: [Fe(3m-salpet)(CN)].CH3OH (1a), [Fe(3e-salpet)(CN)].H2O (1b), while the high-spin compounds were obtained by the reaction of the pseudohalido (other than cyanido) ligands with the [Fe(L5)Cl] complex arising from salicylaldehyde derivatives: [Fe(3Bu5Me-salpet)(NCS)] (2a), [Fe(3m-salpet)(NCO)].CH3OH (2b) and [Fe(3m-salpet)-(N3)] (2c). The compounds exhibiting spin-crossov
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Dalton Transactions (print)
ISSN
1477-9226
e-ISSN
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Volume of the periodical
40
Issue of the periodical within the volume
39
Country of publishing house
GB - UNITED KINGDOM
Number of pages
10
Pages from-to
10090-10099
UT code for WoS article
000295843100018
EID of the result in the Scopus database
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