Nickel(II)complexes with bridged polyamines

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F13%3A33145854" target="_blank" >RIV/61989592:15310/13:33145854 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.poly.2013.03.028" target="_blank" >http://dx.doi.org/10.1016/j.poly.2013.03.028</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.poly.2013.03.028" target="_blank" >10.1016/j.poly.2013.03.028</a>

Result language
angličtina
Original language name
Nickel(II)complexes with bridged polyamines
Original language description
Three nickel(II)complexes [Ni2(u-trien)(trien)2](ClO4)4 (1) ,{[Ni2(u-tren)2(tren)](ClO4)4.3,25H2O}n (2) and [Ni3(u-tren)2(tren)2(H2O)2]Cl6.2H2O (3) (trien=N,N'-bis(2-aminoethyl)ethane-1,2-diamine, tren=N,N'-bis(2-aminoethyl)-1,2-ethanediamine) were synthesized and structurally characterized. Complex 1con-sists of dimeric [Ni2(u-trien)(trien)2 ]4+ cation and perchlorate anions, compound 2 contains polymer chain of cation {[Ni2(u-tren)2(tren)]4+}n, perchlorate anions and uncoordinated water molecules, andstructure of 3 consists of [Ni3(u-tren)2(tren)2(H2O)2]6+ cation, chloride anions and uncoordinated water molecules. All compounds exhibit octahedrally coordinated nickel atoms. Two nickel(II) atoms of [Ni2(u-trien)(trien)2]4+cation in 1 are bridged through one trien ligand, which is bidentate to both nickel(II)atoms. The central Ni(II) atom in complex 3 is associated with peripheral atoms with one arm of tren ligand bonded in tridentate fashion, similarly as two nickel(II) atoms in poly
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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