Ferrate(VI): A Green Chemistry Oxidant for Removal of Antibiotics in Water
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F13%3A33146238" target="_blank" >RIV/61989592:15310/13:33146238 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/bk-2013-1123.ch003" target="_blank" >http://dx.doi.org/10.1021/bk-2013-1123.ch003</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/bk-2013-1123.ch003" target="_blank" >10.1021/bk-2013-1123.ch003</a>
Alternative languages
Result language
angličtina
Original language name
Ferrate(VI): A Green Chemistry Oxidant for Removal of Antibiotics in Water
Original language description
Ferrate(VI) ((FeO42-)-O-VI, Fe(VI)) ion is an environmentally-friendly chemical for water treatment, which can peform a dual function of oxidation and disinfection and forms a non-toxic byproduct, iron(III). This chapter presents an assessment of the potential of ferrate(VI) to oxidize antibiotics (A). The kinetics, stoichiometry, and products and their antibacterial properties are presented. The second-order rate constants, k, of the oxidation reactions at neutral pH were in the range from 5.0 x 10(-1)- 1.5 x 10(3) M(-1)s(-1). At a 10 mg L-1 K2FeO4 dose, half-lives of the oxidation reaction would be in seconds to minutes at a neutral pH. The values of k, and the reaction half-lives, varied with pH. The stoichiometry of the reactions of Fe(VI) with sulfamethoxazole and trimethoprim were 4:1 and 5:1 ([Fe(VI): [A], respectively. Oxidation products of the reactions were found to be relatively less toxic than parent molecule. The oxidized products of trimethoprim showed no significant ant
Czech name
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Czech description
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Classification
Type
D - Article in proceedings
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/ED2.1.00%2F03.0058" target="_blank" >ED2.1.00/03.0058: Regional Centre of Advanced Technologies and Materials</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Article name in the collection
Symposium on Novel Solutions to Water Pollution
ISBN
978-0-8412-2754-5
ISSN
0097-6156
e-ISSN
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Number of pages
14
Pages from-to
31-44
Publisher name
American Chemical Society
Place of publication
Washington
Event location
Denver (CO)
Event date
Aug 28, 2011
Type of event by nationality
WRD - Celosvětová akce
UT code for WoS article
000319300100003