On the Importance and Origin of Aromatic Interactions in Chemistry and Biodisciplines
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F13%3A33148163" target="_blank" >RIV/61989592:15310/13:33148163 - isvavai.cz</a>
Alternative codes found
RIV/61388963:_____/13:00393877
Result on the web
<a href="http://pubs.acs.org/doi/pdf/10.1021/ar300083h" target="_blank" >http://pubs.acs.org/doi/pdf/10.1021/ar300083h</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/ar300083h" target="_blank" >10.1021/ar300083h</a>
Alternative languages
Result language
angličtina
Original language name
On the Importance and Origin of Aromatic Interactions in Chemistry and Biodisciplines
Original language description
Aromatic systems contain both sigma- and pi-electrons, which in turn constitute sigma-and pi-molecular orbitals (MOs). In discussing the properties of these systems, researchers typically refer to the highest occupied and lowest unoccupied MOs, which arepi MOs. The characteristic properties of aromatic systems, such as their low ionization potentials and electron affinities, high polarizabilities and stabilities, and small band gaps (in spectroscopy called the N -} V-1 space), can easily be explained based on their electronic structure. These one-electron properties point to characteristic features of how aromatic systems interact with each other. Unlike hydrogen bonding systems, which primarily interact through electrostatic forces, complexes containing aromatic systems, especially aromatic stacked pairs, are predominantly stabilized by dispersion attraction. The stabilization energy in the benzene dimer is rather small (similar to 2.5 kcal/mol) but strengthens with heteroatom substi
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Accounts of Chemical Research
ISSN
0001-4842
e-ISSN
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Volume of the periodical
46
Issue of the periodical within the volume
4
Country of publishing house
US - UNITED STATES
Number of pages
10
Pages from-to
927-936
UT code for WoS article
000318060000007
EID of the result in the Scopus database
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