Synthesis and structure of tris(dimethyldithiocarbamato) (1,10-phenanthroline)lanthanide complexes
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F13%3A33148199" target="_blank" >RIV/61989592:15310/13:33148199 - isvavai.cz</a>
Alternative codes found
RIV/00216224:14310/13:00068789
Result on the web
<a href="http://dx.doi.org/10.1524/zkri.2013.1625" target="_blank" >http://dx.doi.org/10.1524/zkri.2013.1625</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1524/zkri.2013.1625" target="_blank" >10.1524/zkri.2013.1625</a>
Alternative languages
Result language
angličtina
Original language name
Synthesis and structure of tris(dimethyldithiocarbamato) (1,10-phenanthroline)lanthanide complexes
Original language description
Syntheses and structures of three new lanthanide coordination compounds with dithiocarbamate ligands are reported. The complexes [Ln(Me(2)dtc)(3)(phen)] (Ln = Pr (1), Nd (2) and Gd (3), Me(2)dtc = N,N-dimethyldithiocarbamate and phen = 1,10-phenanthroline) were synthetized by a simple metathesis between lanthanide(III) nitrate and sodium dimethyldithiocarbamate followed by addition of 1,10-phenanthroline without the exclusion of moisture. Single crystal X-ray analysis showed that all three complexes areisostructural, crystallizing in the triclinic space group P (1) over bar. The Ln-S and Ln-N bond lengths decrease in agreement with the decrease in ionic radii across the lanthanide series. Similar structures with Et(2)dtc ligands show no significant effect on the changes of Ln-S bond lengths and also on the S-Ln-S bite angles. The crystal packing of described complexes is formed via pi-pi stacking interactions and C-H center dot center dot center dot S non-covalent contacts.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
S - Specificky vyzkum na vysokych skolach
Others
Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Zeitschrift für Kristallographie
ISSN
0044-2968
e-ISSN
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Volume of the periodical
228
Issue of the periodical within the volume
8
Country of publishing house
DE - GERMANY
Number of pages
5
Pages from-to
369-373
UT code for WoS article
000324128300004
EID of the result in the Scopus database
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