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Synthesis and structure of tris(dimethyldithiocarbamato) (1,10-phenanthroline)lanthanide complexes

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F13%3A33148199" target="_blank" >RIV/61989592:15310/13:33148199 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216224:14310/13:00068789

  • Result on the web

    <a href="http://dx.doi.org/10.1524/zkri.2013.1625" target="_blank" >http://dx.doi.org/10.1524/zkri.2013.1625</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1524/zkri.2013.1625" target="_blank" >10.1524/zkri.2013.1625</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Synthesis and structure of tris(dimethyldithiocarbamato) (1,10-phenanthroline)lanthanide complexes

  • Original language description

    Syntheses and structures of three new lanthanide coordination compounds with dithiocarbamate ligands are reported. The complexes [Ln(Me(2)dtc)(3)(phen)] (Ln = Pr (1), Nd (2) and Gd (3), Me(2)dtc = N,N-dimethyldithiocarbamate and phen = 1,10-phenanthroline) were synthetized by a simple metathesis between lanthanide(III) nitrate and sodium dimethyldithiocarbamate followed by addition of 1,10-phenanthroline without the exclusion of moisture. Single crystal X-ray analysis showed that all three complexes areisostructural, crystallizing in the triclinic space group P (1) over bar. The Ln-S and Ln-N bond lengths decrease in agreement with the decrease in ionic radii across the lanthanide series. Similar structures with Et(2)dtc ligands show no significant effect on the changes of Ln-S bond lengths and also on the S-Ln-S bite angles. The crystal packing of described complexes is formed via pi-pi stacking interactions and C-H center dot center dot center dot S non-covalent contacts.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2013

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Zeitschrift für Kristallographie

  • ISSN

    0044-2968

  • e-ISSN

  • Volume of the periodical

    228

  • Issue of the periodical within the volume

    8

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    5

  • Pages from-to

    369-373

  • UT code for WoS article

    000324128300004

  • EID of the result in the Scopus database