Ferromagnetic Coupling in an Fe[C(SiMe3)3]2/Ferrihydrite Hetero-Mixture Molecular Magnet

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F14%3A33151404" target="_blank" >RIV/61989592:15310/14:33151404 - isvavai.cz</a>
Result on the web
<a href="http://onlinelibrary.wiley.com/doi/10.1002/ejic.201402033/pdf" target="_blank" >http://onlinelibrary.wiley.com/doi/10.1002/ejic.201402033/pdf</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/ejic.201402033" target="_blank" >10.1002/ejic.201402033</a>

Result language
angličtina
Original language name
Ferromagnetic Coupling in an Fe[C(SiMe3)3]2/Ferrihydrite Hetero-Mixture Molecular Magnet
Original language description
Magnetization and low temperature in-field 57Fe Mössbauer spectroscopy measurements have been performed on a Fe[C-(SiMe3)3]2/ferrihydrite hetero-mixture. The results indicate the presence of ferromagnetic coupling of magnetic moments involving Fe[C(SiMe3)3]2 with a hyperfine magnetic field of about 151 T, attributable mainly to the non-frozen atomic orbital contribution. The present findings show the sensitivity of single-ion molecular magnets to local alterations of their lattice-environment and mightexplain and reconcile some of the differences found in the literature for the observed bulk magnetic properties of the title Fe[C(SiMe3)3]2 compound.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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