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Mossbauer investigation of the reaction of ferrate(VI) with sulfamethoxazole and aniline in alkaline medium

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F14%3A33152270" target="_blank" >RIV/61989592:15310/14:33152270 - isvavai.cz</a>

  • Result on the web

    <a href="http://download.springer.com/static/pdf/349/art%253A10.1007%252Fs10751-013-0819-4.pdf?auth66=1424769455_3d685a471239444afb706dea4d457620&ext=.pdf" target="_blank" >http://download.springer.com/static/pdf/349/art%253A10.1007%252Fs10751-013-0819-4.pdf?auth66=1424769455_3d685a471239444afb706dea4d457620&ext=.pdf</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1007/s10751-013-0819-4" target="_blank" >10.1007/s10751-013-0819-4</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Mossbauer investigation of the reaction of ferrate(VI) with sulfamethoxazole and aniline in alkaline medium

  • Original language description

    Mechanisms on the oxidation of sulfamethoxazole (SMX) and aniline by ferrate(VI) (FeVIO4 2?, Fe(VI)) in alkaline medium suggested the formation of Fe(VI)-SMX or Fe(VI)-aniline intermediates, respectively. Fe(V) and Fe(IV) as other intermediate iron species have also been proposed in the mechanism. In this paper, rapid freezeMössbauer spectroscopy was applied in rapidly frozen samples to explore intermediate iron species in the reactions of SMX and aniline with Fe(VI). In both reactions, Fe(VI)-SMX and Fe(VI)-aniline intermediates were not seen in second-minute time scale. Fe(V) and Fe(IV) were also not observed. Fe(III) was the only final species of the reactions.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2014

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Hyperfine Interactions

  • ISSN

    0304-3843

  • e-ISSN

  • Volume of the periodical

    224

  • Issue of the periodical within the volume

    1-3

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    7

  • Pages from-to

    7-13

  • UT code for WoS article

  • EID of the result in the Scopus database