Magnetic properties of anion-radical salt [Fe-II(dipy)(3)](TCNQ)(4)center dot(CH3)(2)CO

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F14%3A33153476" target="_blank" >RIV/61989592:15310/14:33153476 - isvavai.cz</a>
Result on the web
<a href="http://www.sciencedirect.com/science/article/pii/S037967791400143X#" target="_blank" >http://www.sciencedirect.com/science/article/pii/S037967791400143X#</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.synthmet.2014.04.011" target="_blank" >10.1016/j.synthmet.2014.04.011</a>

Result language
angličtina
Original language name
Magnetic properties of anion-radical salt [Fe-II(dipy)(3)](TCNQ)(4)center dot(CH3)(2)CO
Original language description
Magnetic properties of anion-radical TCNQ salt [Fe(dipy)(3)](TCNQ)(4)center dot(CH3)(2)CO have been investigated (dipy is 2,2'-dipyridil). X-ray diffraction data allow presence of two types of TCNQ stacks: tetramerized (diamagnetic) and partly dimerized(paramagnetic). Due to Mossbauer spectroscopy data iron cation appears as two-valent ion in low-spin state. Magnetic susceptibility temperature dependence is described by Bonner Fischer model with additional weak impurity paramagnetism. Susceptibility curve is in good qualitative agreement with ESR spectra.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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