The relationship between the strength of hydrogen bonding and spin crossover behaviour in a series of iron(III) Schiff base complexes

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F15%3A33156252" target="_blank" >RIV/61989592:15310/15:33156252 - isvavai.cz</a>
Result on the web
<a href="http://pubs.rsc.org/en/content/articlehtml/2015/dt/c4dt03400g" target="_blank" >http://pubs.rsc.org/en/content/articlehtml/2015/dt/c4dt03400g</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c4dt03400g" target="_blank" >10.1039/c4dt03400g</a>

Result language
angličtina
Original language name
The relationship between the strength of hydrogen bonding and spin crossover behaviour in a series of iron(III) Schiff base complexes
Original language description
X-ray crystal structures and magnetic properties of an isostructural series of iron(III) Schiff base complexes with the general formula [Fe(L-5)(NCX)].Solv (where H2L5 = N, N'-bis(2-hydroxy-naphthylidene)-1,6-diamino-4-azahexane, X = S, Solv = tetrahydrofuran, 1a; X = S, Solv = methanol and 0.5 pyrazine, 1b; X = S, Solv = butanone, 1c; Solv = N, N'-dimethylformamide, X = S (1d) or X = Se (1d'); X = S, Solv = dimethyl sulfoxide, 1e) are reported. In the crystals, the individual [Fe(L-5)(NCX)] molecules are connected through weak C-H...O, C-H...pi or C-H...S non-covalent contacts into 2D supramolecular networks, while the guest-solvent (Solv) molecules are trapped in the cavities between two adjacent layers, which are furthermore stabilized by N-H...O hydrogen bonds connecting the Solv oxygen atom with the amine group of the [Fe(L-5)(NCX)] molecule, with the N...O distances varying from 2.921(6) angstrom (in 1d') to 3.295(2) angstrom (in 1a). The magnetic properties of the complexes were
Czech name
—
Czech description
—

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
—

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)