Dinuclear and polymeric (mu-formato)nickel(II) complexes: Synthesis, structure, spectral and magnetic properties

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F15%3A33156304" target="_blank" >RIV/61989592:15310/15:33156304 - isvavai.cz</a>
Result on the web
<a href="http://www.sciencedirect.com/science/article/pii/S0277538715001977" target="_blank" >http://www.sciencedirect.com/science/article/pii/S0277538715001977</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.poly.2015.04.010" target="_blank" >10.1016/j.poly.2015.04.010</a>

Result language
angličtina
Original language name
Dinuclear and polymeric (mu-formato)nickel(II) complexes: Synthesis, structure, spectral and magnetic properties
Original language description
Two (mu-formato)nickel(II) complexes [Ni-2(HCOO)(bz)(8)(H2O)(2)](HCOO)(3).4H(2)O (1) and [Ni(tren)(HCOO)] CIO4.H2O (2) were synthesized and characterized by spectroscopic methods. The structure of complexes has been determined by X-ray crystallography. The formato ligand bridges the Ni(II) central atoms forming a dinuclear cation in 1 and a polymeric cationic chain in 2, respectively. The coordination environment of Ni(II) atom is nearly octahedral. Based upon the magnetic data, these two compounds display an exchange interaction of the antiferromagnetic nature along with the zero-field splitting. The results from magnetic analysis of 1 and 2, namely the isotropic exchange constants and the zero-field splitting parameters were further confirmed and studied by DFT method using at B3LYP/def2-TZVP and by CASSCF/NEVPT2, respectively.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/ED2.1.00%2F03.0058" target="_blank" >ED2.1.00/03.0058: Regional Centre of Advanced Technologies and Materials</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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