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Unraveling the performance of dispersion-corrected functionals for the accurate description of weakly bound natural polyphenols

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F15%3A33156864" target="_blank" >RIV/61989592:15310/15:33156864 - isvavai.cz</a>

  • Result on the web

    <a href="http://link.springer.com/article/10.1007%2Fs00894-015-2838-3" target="_blank" >http://link.springer.com/article/10.1007%2Fs00894-015-2838-3</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1007/s00894-015-2838-3" target="_blank" >10.1007/s00894-015-2838-3</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Unraveling the performance of dispersion-corrected functionals for the accurate description of weakly bound natural polyphenols

  • Original language description

    Long-range non-covalent interactions play a key role in the chemistry of natural polyphenols. We have previously proposed a description of supramolecular polyphenol complexes by the B3P86 density functional coupled with some corrections for dispersion. We couple here the B3P86 functional with the D3 correction for dispersion, assessing systematically the accuracy of the new B3P86-D3 model using for that the well-known S66, HB23, NCCE31, and S12L datasets for non-covalent interactions. Furthermore, the association energies of these complexes were carefully compared to those obtained by other dispersion-corrected functionals, such as B(3) LYP-D3, BP86-D3 or B3P86-NL. Finally, this set of models were also applied to a database composed of seven non-covalent polyphenol complexes of the most interest.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/ED2.1.00%2F03.0058" target="_blank" >ED2.1.00/03.0058: Regional Centre of Advanced Technologies and Materials</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2015

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Molecular Modeling

  • ISSN

    1610-2940

  • e-ISSN

  • Volume of the periodical

    21

  • Issue of the periodical within the volume

    11

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    10

  • Pages from-to

    "291-1"-"291-10"

  • UT code for WoS article

    000364527300017

  • EID of the result in the Scopus database