High Performance Liquid Chromatography/Electrochemistry/High Resolution Electrospray Ionization-Mass Spectrometry (HPLC/EC/HR ESI-MS) Characterization of Selected Cytokinins Oxidation Products
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F15%3A33157498" target="_blank" >RIV/61989592:15310/15:33157498 - isvavai.cz</a>
Alternative codes found
RIV/61389030:_____/15:00446194
Result on the web
<a href="http://onlinelibrary.wiley.com/doi/10.1002/elan.201400286/epdf" target="_blank" >http://onlinelibrary.wiley.com/doi/10.1002/elan.201400286/epdf</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/elan.201400286" target="_blank" >10.1002/elan.201400286</a>
Alternative languages
Result language
angličtina
Original language name
High Performance Liquid Chromatography/Electrochemistry/High Resolution Electrospray Ionization-Mass Spectrometry (HPLC/EC/HR ESI-MS) Characterization of Selected Cytokinins Oxidation Products
Original language description
Electrochemistry combined with mass spectrometry represents an emerging analytical technique used to study the oxidation pathway of various drugs and in vivo occurring compounds, continuously showing a capability to generate many known metabolites or newoxidation products. An on-line HPLC/EC/HR ESI-MS method had been used to investigate the oxidation of selected cytokinin compounds. This setup allowed rapid identification and general structure elucidation of the obtained products. An electrochemical oxidation of isopentenyladenine resulted in five products, including hydroxylated and dehydrogenated products, which correlates very well with its in vivo metabolism. Electrochemical conversion of trans-zeatin revealed six products, with two dehydrogenation products corresponding to its in vivo occurring metabolites. cis-Zeatin oxidation in the electrochemical cell gave rise to eight products, resembling similarity to trans-zeatin oxidation. All three compounds underwent a complete turnove
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CB - Analytical chemistry, separation
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Electroanalysis
ISSN
1040-0397
e-ISSN
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Volume of the periodical
27
Issue of the periodical within the volume
2
Country of publishing house
DE - GERMANY
Number of pages
9
Pages from-to
406-414
UT code for WoS article
000349558900018
EID of the result in the Scopus database
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