Fe3O4 (iron oxide)-supported nanocatalysts: synthesis, characterization and applications in coupling reactions

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F16%3A33159714" target="_blank" >RIV/61989592:15310/16:33159714 - isvavai.cz</a>

Result on the web

<a href="http://pubs.rsc.org/en/content/articlepdf/2016/gc/c6gc00864j" target="_blank" >http://pubs.rsc.org/en/content/articlepdf/2016/gc/c6gc00864j</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/c6gc00864j" target="_blank" >10.1039/c6gc00864j</a>

Result language

angličtina

Original language name

Fe3O4 (iron oxide)-supported nanocatalysts: synthesis, characterization and applications in coupling reactions

Original language description

The use of magnetic nanoparticles as a solid support material for the development of magnetically retrievable catalytic systems has led to a dramatic expansion of their potential applications as they enable environmentally-friendly and sustainable catalytic processes. These quasi-homogeneous catalysts possess numerous benefits such as ease of isolation and separation from the desired reaction mixtures using an external magnet and excellent recyclability. Consequently, much effort has been directed towards the synthesis of magnetically isolable nano-sized particles by developing methods such as co-precipitation, thermal decomposition, microemulsion, hydrothermal techniques etc. Further, in order to render them suitable for catalytic applications, several protection strategies such as surfactant/polymer, silica and carbon coating of magnetic nanoparticles or embedding them in a matrix/support have been reported in the literature. This review focuses on the substantial progress made in the fabrication of nano structured catalysts with special emphasis on the protection and functionalization of the magnetite nano particles (Fe3O4). Finally, considering the importance of coupling chemistry in the field of organic synthesis, a broad overview of the applications of these magnetite nanoparticle-based catalysts in several types of coupling reactions has been presented. The future of catalysis lies in the rational design and development of novel, highly active and recyclable nanocomposite catalysts which would eventually pave the pathway for the establishment of green and sustainable technologies.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach

Publication year

2016

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Green Chemistry

ISSN

1463-9262

e-ISSN

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Volume of the periodical

18

Issue of the periodical within the volume

11

Country of publishing house

GB - UNITED KINGDOM

Number of pages

26

Pages from-to

3184-3209

UT code for WoS article

000378178200002

EID of the result in the Scopus database

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